Cement-Based Composites Reinforced with Nanofibrillated Cellulose from Bamboo Organossolv Pulp

$12.50

Cement-Based Composites Reinforced with Nanofibrillated Cellulose from Bamboo Organossolv Pulp

V. da Costa Correia, H. Savastano Jr.

Abstract. Nanofibrillated cellulose has good mechanical performance and high specific surface, which contributes to improve the adhesion between fiber and matrix. The use of cellulose nanofibres as reinforcement of cementitious materials may contribute for improving particle packing, as consequence it helps to decrease porosity and crack growth rate at nanoscale, with corresponding strengthening of the composite. Thus, the aim of this work was to study the effect of 1%, 2% and 3% (by weight) of bamboo nanofibrillated cellulose as reinforcement of cementitious composites in comparison to composites reinforced with 8% of bamboo pulp. The cementitious composites were produced by slurry-dewatering method and they were subjected to physical, mechanical e microstructural analyses at 8 days of age. The results indicated that on average 3% of nanofibrillated cellulose showed higher strength than composites reinforced with 1% and 2% of fibers. Modulus of rupture of composites reinforced with 8% of bamboo pulp was lower than composites reinforced with nanofibrillated cellulose. In relation to toughness, composites reinforced with nanofibrillated cellulose were more fragile than composites reinforced with pulp. This is due to the lower amount of nanofibrillated cellulose used as reinforcement, and due to the lower length of these fibers in comparison to pulp fibers, which reduces the pull-out energy involved in the fracture. Considering the intrinsic characteristics of the nanofibrillated cellulose, this vegetable fiber showed to be a promising material for use as nanoreinforcement of the cement-based composites, however, more studies are necessary about the optimum amount of nanofibers for improving the toughness of the cementitious composites.

Keywords
Nanofibrillated Cellulose, Bamboo, Cement-Based Composites

Published online , 9 pages
Copyright © 2018 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: V. da Costa Correia, H. Savastano Jr., ‘Cement-Based Composites Reinforced with Nanofibrillated Cellulose from Bamboo Organossolv Pulp’, Materials Research Proceedings, Vol. 7, pp 119-127, 2018

DOI: https://dx.doi.org/10.21741/9781945291838-12

The article was published as article 12 of the book Non-Conventional Materials and Technologies

References
[1] Makar JM, Margeson JC, Luh J. Carbon nanotube/cement composite—early results and potential applications. Proceedings of International Conference on Construction Materials: Performance, Innovation and Structural Implications. Ottawa: Institute for Research in Construction, National Research Council Canada, 2005. p. 1–10.
[2] Li GY, Wang PM, Zhao X. Mechanical behavior and microstructure of cement composites incorporating surface-treated multi-walled carbon nanotubes. Carbon 2005; 43: 1239-1245. https://doi.org/10.1016/j.carbon.2004.12.017
[3] Yakovlev G, Kerienė J, Gailius A, Girniene I. Cement based foam concrete reinforced by carbon nanotubes. Mater Sci+ 2006; 12 (2): 147-151.
[4] Konsta-Gdoutos MS, Metaxa ZS, Shah SP. Multi-scale mechanical and fracture characteristics and early-age strain capacity of high performance carbon nanotube/cement nanocomposites. Cement Concrete Comp 2010; 32: 110-115. https://doi.org/10.1016/j.cemconcomp.2009.10.007
[5] Metaxa ZS, Konsta-Gdoutos MS, Shah SP. Carbon nanofiber cementitious composites: Effect of debulking procedure on dispersion and reinforcing efficiency. Cement Concrete Comp 2013; 36: 25-32. https://doi.org/10.1016/j.cemconcomp.2012.10.009
[6] Galao O, Baeza FJ, Zornoza E, Garcés P. Strain and damage sensing properties on multifunctional cement composites with CNF admixture. Cement Concrete Comp 2014; 46: 90-98. https://doi.org/10.1016/j.cemconcomp.2013.11.009
[7] Coutts RSP. Fibre–matrix interface in air-cured wood-pulp fibre– cement composites. J Mater Sci Lett 1987; 6: 140-142. https://doi.org/10.1007/BF01728964
[8] Correia VC, Santos SF, Tonoli GHD, Savastano Jr H. Characterization of Vegetable Fibres and their Application in Cementitious Composites. In: Harries KA, Sharma B, editors. Nonconventional and Vernacular Construction Materials: Characterisation, Properties and Applications. Woodhead Publishing, 2016. p. 83-110. https://doi.org/10.1016/B978-0-08-100038-0.00004-4
[9] Kamel S. Nanotechnology and its applications in lignocellulosic composites, a mini review. Express Polym Lett 2007; 1(9): 546-575. https://doi.org/10.3144/expresspolymlett.2007.78
[10] Correia VC, Santos V, Sain M, Santos SF, Leão AL, Savastano Jr H. Grinding process for the production of nanofibrillated cellulose based on unbleached and bleached bamboo organosolv pulp. Cellulose 2016; 23: 2971 – 2987. https://doi.org/10.1007/s10570-016-0996-9
[11] Ardanuy M, Claramunt J, Arévalo R, Parés F. Nanofibrillated cellulose (NFC) as a potential reinforcement for high performance cement mortar composites. BioResources 2012; 73: 3883-3894.
[12] Onuaguluchi O, Panesar DK, Sain M. Properties of nanofibre reinforced cement composites. Constr Build Mater 2014; 63: 119-124. https://doi.org/10.1016/j.conbuildmat.2014.04.072
[13] Thomson SL, O’Callaghan DJ, Westland JA, Su B. Method of making a fiber cement board with improved properties of the product. US Patent 2010/0162926 AL, 01 July 2010.
[14] Savastano Jr H, Warden PG, Coutts RSP. Brazilian waste fibres as reinforcement for cement-based composites. Cement Concrete Comp 2000; 22 (5): 379-384. https://doi.org/10.1016/S0958-9465(00)00034-2
[15] Correia VC, Santos SF, Mármol G, Curvelo AAS, Savastano Jr H. Potential of bamboo organosolv pulp as reinforcement element in fiber-cement. Constr Build Mater 2014; 72: 65-71. https://doi.org/10.1016/j.conbuildmat.2014.09.005
[16] Almeida AEFS, Tonoli GHD, Santos SF, Savastano Jr H. Improved durability of vegetable fiber reinforced cement composite subject to accelerated carbonation at early age. Cement Concrete Comp 2013; 42: 49-58. https://doi.org/10.1016/j.cemconcomp.2013.05.001
[17] Tonoli GHD, Fuente E, Monte C, Savastano Jr H, Rocco Lahr FA, Blanco A. Effect of fibre morphology on flocculation of fibre-cement suspensions. Cement Concrete Res 2009; 39: 1017-1022. https://doi.org/10.1016/j.cemconres.2009.07.010
[18] Tonoli GHD, Joaquim AP, Arsène M-A, Bilba K, Savastano Jr H. Performance and Durability of Cement Based Composites Reinforced with Refined Sisal Pulp. Mater Manuf Process 2007; 22: 149-156. https://doi.org/10.1080/10426910601062065
[19] ASTM C 948 standard test method for dry and wet bulk density, water absorption, and apparent porosity of thin sections of glass-fibre reinforced concrete, 1982.
[20] Yoo D-Y, Kim S, Park G-J, Park J-J, Kim S-W. Effects of fiber shape, aspect ratio, ad volume fraction on flexural behavior of ultra-high-performance fiber-reinforced cement composites. Compos Struct 2017; 174: 375-388. https://doi.org/10.1016/j.compstruct.2017.04.069
[21] Bentur A, Mindess S. Introduction. In: Bentur A, Mindess S, editor. Fibre Reinforced Cementitious Composites, 2nd ed. New York: Taylor &Francis, 2007. p. 1-10.