Conducting polymer composites for supercapacitors
Angesh Chandra, Archana Chandra
Synthesis, ion conduction and device fabrications of some ion conducting composite polymer electrolytes (CPEs) are reported in the present chapter. The different experimental and theoretical tools have been explained for preparation and ion conduction mechanism of CPEs. The working principle of some polymer electrolyte based supercapacitors has been explained, as reported by research work.
Keywords
Ion Conducting Polymers, Composites, Ionic Conductivity, Supercapacitor
Published online 1/15/2018, 17 pages
DOI: https://dx.doi.org/10.21741/9781945291531-8
Part of Nanocomposites for Electrochemical Capacitors
References
[1] B. E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic Publishers, New York 1999. https://doi.org/10.1007/978-1-4757-3058-6
[2] Wen Lu, Rachel Hartman, Liangti Qu, Liming Dai, nanocomposite electrodes for high-performance supercapacitors, J. Phys. Chem. Lett. 2 (2011) 655–660. https://doi.org/10.1021/jz200104n
[3] H. Gao, K. Lian, Proton-conducting polymer electrolytes and their applications in solid supercapacitors: A review, RSC Adv. 4 (2014) 33091-33113. https://doi.org/10.1039/C4RA05151C
[4] R.C. Agrawal, G.P. Pandey, Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview, J. Phys. D: Appl. Phys. 41 (2008) 223001-223018. https://doi.org/10.1088/0022-3727/41/22/223001
[5] G.B. Appetecchi, F. Croce, J. Hassoun, B. Scrosati, M. Salomon, F. Cassel, Hot-pressed, dry, composite, PEO-based electrolyte membranes I. Ionic conductivity characterization, J. Power Sourc. 114 (2003) 105-112. https://doi.org/10.1016/S0378-7753(02)00543-8
[6] A. Chandra, A. Chandra, K. Thakur, Preparation and characterization of hot-pressed Na+ ion conducting nano-composite polymer electrolytes, Indian J. Pure & Appl. Phys. 51 (2013) 44-48.
[7] A. Chandra, A. Chandra, K. Thakur, Synthesis and ion conduction mechanism on hot-pressed sodium ion conducting nano composite polymer electrolytes, Arabian J. Chem. 9 (2016) 400-407. https://doi.org/10.1016/j.arabjc.2013.07.014
[8] A. Chandra, A. Chandra, S.S. Thakur, Hot-pressed nano-composite polymer electrolytes: (1-x) [70PEO:30KBrO3]: x SiO2, Indian J. Pure & Appl. Phys. 49 (2011) 698-702.
[9] A. Chandra, A. Chandra, K. Thakur, Synthesis, characterization and polymer battery fabrication of hot-pressed nano composite polymer electrolytes, Composites: Part B 60 (2014) 292-296. https://doi.org/10.1016/j.compositesb.2013.12.071
[10] A. Chandra, Ion conducting nano-composite polymer electrolytes: synthesis and ion transport characterization, Polym. Bull. 74 (2017) in press. https://doi.org/10.1007/s00289-017-1986-2
[11] R.C. Agrawal, A. Chandra, Ion transport and electrochemical cell performance studies on hot-press-synthesized Ag+ ion conducting electroactive polymeric membranes: (1-x) PEO: x [0.7(0.75AgI:0.25 AgCl):0.3 MI], J. Phys. D: Appl. Phys. 40 (2007) 7024-7031. https://doi.org/10.1088/0022-3727/40/22/024
[12] A. Chandra, R.C. Agrawal, Y.K. Mahipal, Ion transport property studies on PEO-PVP blended solid polymer electrolyte membranes, J. Phys. D: Appl. Phys. 42 (2009) 135107-135110. https://doi.org/10.1088/0022-3727/42/13/135107
[13] A. Chandra, A. Chandra, Hot-pressed polymer electrolytes: Synthesis and characterization, Lambert Academic Pub., Germany, 2010.
[14] X. Yang, F. Zhang, L. Zhang, T. Zhang, Y. Huang, Y. Chen, A high performance graphene oxide-doped ion gel as gel polymer electrolyte for all-solid-state supercapacitor applications, Adv. Funct. Mater. 23 (2013) 3353–3360. https://doi.org/10.1002/adfm.201203556
[15] X. Yang, L. Zhang, F. Zhang, T. Zhang, Y. Huang, Y. Chen, A high-performance all-solid-state supercapacitor with graphene-doped carbon material electrodes and a graphene oxide-doped ion gel electrolyte, Carbon 72 (2014) 381-386. https://doi.org/10.1016/j.carbon.2014.02.029
[16] Y.N. Shudhakar, M. Selvakumar, D. Krishna Bhat, Lithium salts doped biodegradable gel polymer electrolytes for supercapacitor application, J. Mater. Environ. Sci. 6 (2015) 1218-1227.
[17] W. Lue, R. Hartman, Nanocomposite electrodes for high-preformance supercapacitors, J. Phys. Chem. Lett. 2 (2011) 655-660. https://doi.org/10.1021/jz200104n
[18] J.P.C. Trigueiro, R.S. Borges, R.L. Lavall, H.D.R. Calado, G.G. Silva, Polymeric nanomaterials as electrolyte and electrodes in supercapacitors, Nano Research 2 (2009) 733-739. https://doi.org/10.1007/s12274-009-9080-1
[19] E. Frackowiak, F. Beguin, Carbon materials for the electrochemical storage of energy in capacitors, Carbon 39 (2001) 937-950. https://doi.org/10.1016/S0008-6223(00)00183-4
[20] C.S. Du, J. Yeh, N. Pan, High power density supercapacitors using locally aligned carbon nanotube electrodes, Nanotechnology 16 (2005) 350-353. https://doi.org/10.1088/0957-4484/16/4/003
[21] H. Zhang, G.P. Cao, Y.S. Yang, Electrochemical properties of ultra-long, aligned, carbon nanotube array electrode in organic electrolyte, J. Power Sources 172 (2007) 476-480. https://doi.org/10.1016/j.jpowsour.2007.07.060