Ion-exchange kinetics of alkaline metals on the surface of carboxymethyl cellulose Sn(IV) phosphate composite cation exchanger
Ali Mohammad, Mohd Imran Ahamed, Arshi Amin, Inamuddin
Approximated Nernst-Plank equation was used to study the kinetics and mechanism for the ion-exchange processes like Mg2+-H+, Ca2+-H+, Sr2+-H+ and Ba2+-H+ on the surface of carboxymethyl cellulose Sn(1V) phosphate composite nano-rod like cation-exchanger. The kinetics of exchange was favoured under the particle diffusion controlled phenomenon. Some physical parameters i.e. fractional attainment of equilibrium U(), self diffusion coefficients (Do), energy of activation (Ea) and entropy of activation (ΔS*) have been estimated.
Keywords
Organic–Inorganic Composite Materials, Cation-Exchanger, Ion-Exchange Kinetics, Carboxymethyl Cellulose Sn(IV) Phosphate
Published online 4/25/2017, 6 pages
Copyright © 2016 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA
Citation: Ali Mohammad, Mohd Imran Ahamed, Arshi Amin, Inamuddin, ‘Ion-exchange kinetics of alkaline metals on the surface of carboxymethyl cellulose Sn(IV) phosphate composite cation exchanger’, Materials Research Foundations, Vol. 15, pp 34-39, 2017
DOI: https://dx.doi.org/10.21741/9781945291333-2
The article was published as article 2 of the book Applications of Adsorption and Ion Exchange Chromatography in Waste Water Treatment
References
[1] H. Li, Z. Zheng, M. Cao, R. Cao, Stable gold nanoparticle encapsulated in silica-dendrimers organic–inorganic hybrid composite as recyclable catalyst for oxidation of alcohol, Microporous Mesoporous Mater. 136 (2010) 42–49.
[2] K. Dallmann, R. Buffon, Sol–gel derived hybrid materials as heterogeneous catalysts for the epoxidation of olefins, Catal. Commun. 1 (2000) 9–13.
[3] S. Chaudhari, P.P. Patil, Corrosion protective poly(o-ethoxyaniline) coatings on copper, Electrochim. Acta. 53 (2007) 927–933.
[4] Y. Zhang, H. Zhang, C. Bi, X. Zhu, An inorganic/organic self-humidifying composite membranes for proton exchange membrane fuel cell application, Electrochim. Acta. 53 (2008) 4096–4103.
[5] J.L. Malers, M.-A. Sweikart, J.L. Horan, J.A. Turner, A.M. Herring, Studies of heteropoly acid/polyvinylidenedifluoride–hexafluoroproylene composite membranes and implication for the use of heteropoly acids as the proton conducting component in a fuel cell membrane, J. Power Sources. 172 (2007) 83–88.
[6] A.A. Khan, Inamuddin, Applications of Hg(II) sensitive polyaniline Sn(IV) phosphate composite cation-exchange material in determination of Hg2+ from aqueous solutions and in making ion-selective membrane electrode, Sensors Actuators B Chem. 120 (2006) 10–18.
[7] I. Nabi, S.A. Alam, Z., A Cadmium Ion-selective Membrane Electrode Based on Strong Acidic Organic-inorganic Composite Cation-exchanger: Polyaniline Ce(IV) Molybdate, Sens. Transd. J. (S T E-Digest). 2008 (92AD) 87.
[8] C. Guizard, A. Bac, M. Barboiu, N. Hovnanian, Hybrid organic-inorganic membranes with specific transport properties, Sep. Purif. Technol. 25 (2001) 167–180.
[9] Z. Alam, Inamuddin, S.A. Nabi, Synthesis and characterization of a thermally stable strongly acidic Cd(II) ion selective composite cation-exchanger: Polyaniline Ce(IV) molybdate, Desalination. 250 (2010) 515–522.
[10] P. Lacan, C. Guizard, P. Le Gall, D. Wettling, L. Cot, Facilitated transport of ions through fixed-site carrier membranes derived from hybrid organic-inorganic materials, J. Memb. Sci. 100 (1995) 99–109..
[11] A. Nilchi, A. Khanchi, H. Atashi, A. Bagheri, L. Nematollahi, The application and properties of composite sorbents of inorganic ion exchangers and polyacrylonitrile binding matrix, J. Hazard. Mater. 137 (2006) 1271–1276.
[12] A. Mohammad, Inamuddin, A. Amin, Surfactant assisted preparation and characterization of carboxymethyl cellulose Sn(IV) phosphate composite nano-rod like cation exchanger, J. Therm. Anal. Calorim. 107 (2012) 127–134.
[13] K.G. Varshney, A.A. Khan, S. Rani, Forward and reverse ion-exchange kinetics for Na+-H+ and K+-H+ exchanges on crystalline antimony (V) silicate, Colloids and Surfaces. 25 (1987) 131–137.
[14] S. Kodama, K. Fukui, A. Mazume, Relation of Space Velocity and Space Time Yield, Ind. Eng. Chem. 45 (1953) 1644–1648.
[15] F. Helfferich, M.S. Plesset, Ion Exchange Kinetics. A Nonlinear Diffusion Problem, J. Chem. Phys. 28 (1958) 418–424.
[16] M.S. Plesset, F. Helfferich, J.N. Franklin, Ion Exchange Kinetics. A Nonlinear Diffusion Problem. II. Particle Diffusion Controlled Exchange of Univalent and Bivalent Ions, J. Chem. Phys. 29 (1958) 1064–1069.