Sol-gel synthesis and characterization of samarium and manganese substituted calcium hydroxyapatite, Ca10(PO4)6(OH)2
I. Bogdanoviciene, A. Beganskiene, A. Kareiva
An aqueous sol-gel synthesis route has been developed to prepare samarium and manganese substituted calcium hydroxyapatite (Ca10-xMx(PO4)6(OH)2, CHAp:M) samples. The final products were obtained by calcination of the dry Ca(M)-P-O precursor gels for 5 h at 1000 °C. The phase transformations, composition and structural changes in the polycrystalline samples were studied by infrared (IR) spectroscopy, X-ray powder diffraction (XRD) analysis, scanning electron microscopy (SEM), UV-visible reflection spectroscopy and luminescence measurements. It was demonstrated that phase purity, morphology and optical properties of the end products highly depends on the amount of lanthanide or transition metal in CHAp.
Keywords
Calcium Hydroxyapatite, Sol-Gel Processing, Substitution Effect, Samarium, Manganese
Published online 1/1/2017, 14 pages
DOI: https://dx.doi.org/10.21741/9781945291135-4
Part of Contemporary Dielectric Materials
References
[1] D. Green, D. Walsh, S. Mann, R.O.C. Oreffo. Bone.30 (2002) 810. https://dx.doi.org/10.1016/S8756-3282(02)00727-5
[2] A.C. Lawson, J.T. Czernuszka, Proc. Instr. Mech. Eng. 212 (1998) 413. https://dx.doi.org/10.1243/0954411981534187
[3] A. Anwar, M.N. Asghar, Q. Kanwal, M. Kazmi, A. Sadiqa, J. Molec. Struct. 1117 (2016) 283. https://dx.doi.org/10.1016/j.molstruc.2016.03.061
[4] A. Bigi, E. Boanini, K. Rubini, J. Solid State Chem. 177 (2004) 3092. https://dx.doi.org/10.1016/j.jssc.2004.05.018
[5] J. Liu, K. Li, H. Wang, M. Zhu, H. Yan, Chem. Phys. Lett. 396 (2004) 429. https://dx.doi.org/10.1016/j.cplett.2004.08.094
[6] C.E. Fowler, M. Li, S. Mann, H.C. Margolis, J. Mater. Chem. 15 (2005) 3317. https://dx.doi.org/10.1039/b503312h
[7] G. Goller, F.N. Oktar, S. Agathopoulos, D.U. Tulyaganov, J.M.F. Ferreira, E.S. Kayali, I. Peker, J. Sol-Gel Sci. Technol. 37 (2006) 111. https://dx.doi.org/10.1007/s10971-006-6428-9
[8] J. Trinkunaite-Felsen, A. Prichodko, M. Semasko, R. Skaudzius, A. Beganskiene, A Kareiva, Adv. Powder Technol. 26(2015) 1287. https://dx.doi.org/10.1016/j.apt.2015.07.002
[9] I. Mayer, J.D.B. Featherstone, J. Cryst. Growth. 219 (2000) 98. https://dx.doi.org/10.1016/S0022-0248(00)00608-4
[10] S. Ben Abdelkader, I. Khattech, C. Rey, M. Jemal, Thermochim. Acta. 376 (2001) 25. https://dx.doi.org/10.1016/S0040-6031(01)00565-2
[11] E. Garskaite, K. A. Gross, S. W. Yang, Thomas C. K. Yang, J. C. Yang, A. Kareiva, Cryst. Eng. Commun. 16 (2014) 3950. https://dx.doi.org/10.1039/c4ce00119b
[12] A. Serret, M.V. Cabanas, M. Vallet-Regi, Chem. Mater. 12 (2000) 3836. https://dx.doi.org/10.1021/cm001117p
[13] I. Bogdanoviciene, M. Cepenko, R. Traksmaa, A. Kareiva, K. Tõnsuaadu. J. Therm. Anal. Calorim. 121 (2015) 107.
https://dx.doi.org/10.1007/s10973-015-4507-2
[14] G. Ciobanu, A.M. Bargan, C. Luca, JOM. 67 (2015) 2534. https://dx.doi.org/10.1007/s11837-015-1467-8
[15] F.B. Bagam Bisa, H.F . Kappert, W. Schili, J. Oral. Maxillofac. Surg.52 (1994)52. https://dx.doi.org/10.1016/0278-2391(94)90015-9
[16] I. Bogdanoviciene, M. Misevicius, A. Kareiva, K.A. Gross,Thomas C.K. Yang, G.-T. Pan, H.-W. Fang, J.-C. Yang, Adv. Sci. Technol. 86 (2013) 22. https://dx.doi.org/10.4028/www.scientific.net/AST.86.22
[17] K. Boughzala, K. Bouzouita, Comptes Rendus Chim. 18 (2015) 858. https://dx.doi.org/10.1016/j.crci.2014.11.011
[18] G. Ciobanu, A. M. Bargan, C. Luca, Ceram. Int. 41 (2015) 12192. https://dx.doi.org/10.1016/j.ceramint.2015.06.040
[19] C. Rosticher, B. Viana, T. Maldiney, C. Richard, C. Chaneac, J. Lumin. 170 (2016) 460. https://dx.doi.org/10.1016/j.jlumin.2015.07.024
[20] J. Kolmas, S. Krukowski, A. Laskus, M. Jurkitewicz, Ceram. Int. 42 (2016) 2472. https://dx.doi.org/10.1016/j.ceramint.2015.10.048
[21] L. Medvecky, R. Stulajterova, L. Parilak, J. Trpcevska, J. Durisin, S.M. Barinov, Colloids Surf. A: Physicochem. Eng. Aspects.281 (2006) 221. https://dx.doi.org/10.1016/j.colsurfa.2006.02.042
[22] E. Boanini, M. Gazzano, A. Bigi, Acta Biomaterialia.6 (2010) 1882. https://dx.doi.org/10.1016/j.actbio.2009.12.041
[23] D. Bani, A. Bencini, M.C. Bergonzi, A.R. Bilia, C. Guccione, M. Severi, R. Udisti, B. Valtancoli, J. Pharmaceut. Biomed. Anal. 106 (2015) 197. https://dx.doi.org/10.1016/j.jpba.2014.11.021
[24] S. Sakirzanovas, A. Katelnikovas, D. Dutczak, A. Kareiva, T. Jüstel, J. Lumin.132 (2012) 141. https://dx.doi.org/10.1016/j.jlumin.2011.08.011
[25] A. Stanulis, A. Katelnikovas, D. Enseling, D. Dutczak, S. Sakirzanovas, M. Van Bael, A. Hardy, A. Kareiva, T. Jüstel, Opt. Mater. 36 (2014) 1146. https://dx.doi.org/10.1016/j.optmat.2014.02.018
[26] S. Chahar, V.B. Taxak, M. Dalal, S. Singh, S.P. Khatkar, Mater. Res. Bull. 77 (2016) 91. https://dx.doi.org/10.1016/j.materresbull.2016.01.027
[27] J. Livage, M. Henry, C. Sanchez,Progr. Solid State Chem.18 (1988)259. https://dx.doi.org/10.1016/0079-6786(88)90005-2
[28] B.L. Cushing, V.L. Kolesnichenko, C.J. O‘Connor, Chem. Rev.104 (2004)3893. https://dx.doi.org/10.1021/cr030027b
[29] J.D. Mackenzie, E.P. Bescher, Acc. Chem.Res.40 (2007)810. https://dx.doi.org/10.1021/ar7000149
[30] C. Yu, D. Cai, K. Yang, J.C. Yu, Y. Zhou, C. Fan, J. Phys. Chem. Solids. 71 (2010) 1337. https://dx.doi.org/10.1016/j.jpcs.2010.06.001
[31] A. Kareiva, Mater. Sci. (Medziagotyra).17 (2011) 428.
[32] T.K. Thirumalaisamy, S. Saravanakumar, S. Butkute, A. Kareiva, R. Saravanan, J. Mater. Sci.: Mater. Electron. 27 (2016) 1920. https://dx.doi.org/10.1007/s10854-015-3974-3
[33] I. Bogdanoviciene, A. Beganskiene, K. Tõnsuaadu, J. Glaser, H-J. Meyer, A. Kareiva, Mater. Res. Bull. 41 (2006) 1754. https://dx.doi.org/10.1016/j.materresbull.2006.02.016
[34] I. Bogdanoviciene, K. Tõnsuaadu, A. Kareiva, Polish J. Chem. 83 (2009) 47.
[35] I. Bogdanoviciene, K. Tõnsuaadu, V. Mikli,I. Grigoraviciute-Puroniene, A. Beganskiene, A. Kareiva. Centr. Eur. J. Chem.8 (2010)1323.
[36] A. Antonakos, E. Liarokapis, T. Leventouri, Biomater. 28 (2007) 3043. https://dx.doi.org/10.1016/j.biomaterials.2007.02.028
[37] T.-M.G. Chu, J.W. Halloran, S.J. Hollister, S.E. Feinberg, J. Mater. Sci.: Mater. Med.12 (2001)471. https://dx.doi.org/10.1023/A:1011203226053
[38] A.C. Tas, F. Aldinger, J. Mater Sci:Mater Med. 16 (2005) 167. https://dx.doi.org/10.1007/s10856-005-5919-5
