Morphological properties of Zinc Oxide loaded electrospun Polyethylene furan-2,5-dicarboxylate/ Polyhydroxybutyrate electrospun nanofibers for potential food packaging

Morphological properties of Zinc Oxide loaded electrospun Polyethylene furan-2,5-dicarboxylate/ Polyhydroxybutyrate electrospun nanofibers for potential food packaging

James KEGERE, Athira V. ARAMUGHAN, Bismi Phasaldudeen, Akmal Nazir, Ioannis Zuburtikudis, Muhammad Z. IQBAL

Abstract. There have been growing safety concerns in society over the utilization of recent technologies, especially in food and medicine. In the food sector, the salient technologies are biotechnology and nanotechnology. Nanotechnology is particularly intriguing because of the puissant properties that are derived from reducing materials to the bottom. One such application is found in food packaging, where nanoparticles have been utilized extensively to counter food contamination and adulterations, along with smart monitoring properties. These nanoscale materials are as great as they present challenges when they excessively leak into the food systems themselves. In this work, we designed electrospun nanofibers loaded with ZnO nanoparticles to elucidate the chemical interaction of the nanoparticles, suitability in applications such as food packaging by establishing the effect of such composites on key parameters that are of paramount focus in the food packaging industry. Our findings indicate improvement of morphological properties of PHB by PEF and branching effect caused by addition of ZnO.Attempts at antibacterial studies didn’t yield significant results, but the potential to enhance this property through light-assisted bactericidal action exists.

Keywords
PEF, PHB, Nanofiber Composites, Zinc Oxide, Electrospinning, Release Kinetics

Published online 6/20/2026, 5 pages
Copyright © 2026 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: James KEGERE, Athira V. ARAMUGHAN, Bismi Phasaldudeen, Akmal Nazir, Ioannis Zuburtikudis, Muhammad Z. IQBAL, Morphological properties of Zinc Oxide loaded electrospun Polyethylene furan-2,5-dicarboxylate/ Polyhydroxybutyrate electrospun nanofibers for potential food packaging, Materials Research Proceedings, Vol. 67, pp 719-723, 2026

DOI: https://doi.org/10.21741/9781644904176-99

The article was published as article 99 of the book Climate Action and Sustainability

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] K. J. Figueroa-Lopez, C. Prieto, M. Pardo-Figuerez, L. Cabedo, and J. M. Lagaron, “Development and Characterization of Electrospun Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Biopapers Containing Cerium Oxide Nanoparticles for Active Food Packaging Applications,” Nanomaterials, vol. 13, no. 5, Mar. 2023. https://doi.org/10.3390/nano13050823.
[2] R. Valizadeh, M. Zandi, A. Ganjloo, and N. Dardmeh, “Bioactive multilayer film based on the sage seed gum-gelatin, TiO2 and electrospun zein fibers encapsulating pomegranate peel extract,” Int J Biol Macromol, vol. 283, Dec. 2024. https://doi.org/10.1016/j.ijbiomac.2024.137826.
[3] J. L. Castro Mayorga, M. J. Fabra Rovira, L. Cabedo Mas, G. Sánchez Moragas, and J. M. Lagarón Cabello, “Antimicrobial nanocomposites and electrospun coatings based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and copper oxide nanoparticles for active packaging and coating applications,” J Appl Polym Sci, vol. 135, no. 2, Jan. 2018. https://doi.org/10.1002/app.45673.
[4] K. Petersen et al., “Potential of biobased materials for food packaging.”
[5] M. Arkoun, F. Daigle, R. A. Holley, M. C. Heuzey, and A. Ajji, “Chitosan-based nanofibers as bioactive meat packaging materials,” Packaging Technology and Science, vol. 31, no. 4, pp. 185–195, Apr. 2018. https://doi.org/10.1002/pts.2366.
[6] S. Ataei, P. Azari, A. Hassan, B. Pingguan-Murphy, R. Yahya, and F. Muhamad, “Essential Oils-Loaded Electrospun Biopolymers: A Future Perspective for Active Food Packaging,” Advances in Polymer Technology, vol. 2020, pp. 1–21, Feb. 2020. https://doi.org/10.1155/2020/9040535.
[7] Aslam, R., Sivapragasam, N., Lawal, K. G., Ahmed, Z. F., & Maqsood, S. (2025). Bionanocomposite Films from Camel Skin Gelatin Reinforced with Tannic Acid and Date Seed Nanocellulose. Food Biophysics, 20(3), 119, doi.org/10.1007/s11483-025-10000-z‏
[8] Kaur, N., Ahmed, Z. F. R., Somasundram, C. Razali, Z., (2024) Sustainable Aloe vera/Chitosan-based Edible Coatings Reduce Postharvest Loss of Stored Fresh Figs (Ficus carica L.). Frontiers in Sustainable Food System 8, 1459600, doi.org/10.3390/polym16020242
[9] Kaur, N.; Somasundram, C.; Razali, Z.; Mourad, A.-H.I.; Hamed, F.; Ahmed, Z.F.R. (2024) Aloe vera/Chitosan-Based Edible Film with Enhanced Antioxidant, Antimicrobial, Thermal, and Barrier Properties for Sustainable Food Preservation. Polymers 16, 242, doi.org/10.3390/polym16020242.
[10] K. E, M. C. K, B. P, T. S. A, and J. C. R. I, “Biocompatible silver nanoparticles/poly(vinyl alcohol) electrospun nanofibers for potential antimicrobial food packaging applications,” Food Packag Shelf Life, vol. 21, Sep. 2019. https://doi.org/10.1016/j.fpsl.2019.100379, .
[11] S. Amjadi, S. Emaminia, S. Heyat Davudian, S. Pourmohammad, H. Hamishehkar, and L. Roufegarinejad, “Preparation and characterization of gelatin-based nanocomposite containing chitosan nanofiber and ZnO nanoparticles,” Carbohydr Polym, vol. 216, pp. 376–384, Jul. 2019. https://doi.org/10.1016/j.carbpol.2019.03.062.
[12] F. Shahmohammadi Jebel and H. Almasi, “Morphological, physical, antimicrobial and release properties of ZnO nanoparticles-loaded bacterial cellulose films,” Carbohydr Polym, vol. 149, pp. 8–19, Sep. 2016. https://doi.org/10.1016/j.carbpol.2016.04.089.
[13] S. Thongkham, “Environmentally Friendly nanomembrane from PEF-PHBv composites: Preparation and investigation of morphologies, thermal, and mechanical properties,” 2023. https://doi.org/10.21203/rs.3.rs-3673950/v1.
[14] Al Yabhouni, L., Subhan, A., Mourad, A. H. I., Francis, D. V., Ahmed, Z. F., & Ramachandran, T. (2025). Antibacterial and photocatalytic activity of chitosan encapsulated Ag/ZnO ternary nanocomposites. Next Research, 100451.
[15] Alhindaassi, H., Almheiri, M. H., Alrayssi, T. A., Francis, D. V., Ali, M., Jaleel, A.,& Ahmed, Z. F. (2025). Ghaf microgreen: a novel functional food with enhanced nutritional content via nanoparticle-seed priming. Future Foods, 100774.”.