Enhancing knock limit in hydrogen–gasoline dual fuel engine through methanol addition and injection pressure optimization
S.T.P PURAYIL, SAB AL-OMARI, E. ELNAJJAR
Abstract. Hydrogen-enriched engines have gained considerable attention due to their superior combustion and emission characteristics. However, the unique properties of hydrogen make it more susceptible to combustion knock, particularly at higher hydrogen fractions, thereby limiting its practical application. This study investigates the influence of methanol–gasoline blending and varying fuel injection pressures on engine performance and emission characteristics. Nevertheless, limited research has been conducted on the collective effect of methanol–gasoline blends and injection pressure variation on the knock resistance of hydrogen-enriched spark-ignition engines. Gasoline was blended with methanol at volumetric proportions of 20% and 50% and injected at fuel pressures of 80 and 140 bar. Hydrogen was supplied through the intake manifold in steps of 2 litres per minute (L/min) until combustion knock was detected. Results showed that both increasing the methanol proportion and raising the injection pressure delayed the knock occurrence, with the most significant improvement obtained when these strategies were applied together. While higher methanol proportion and greater injection pressure decreased brake thermal efficiency, cylinder pressure and NOx formation, the introduction of hydrogen counteracted these effects by enhancing engine output. A key finding was that combining a 50% methanol fraction with 140 bar injection pressure pushed the hydrogen knock limit from 14 L/min to 20 L/min. These results demonstrate a practical route to extending hydrogen utilization and supporting cleaner, more efficient engine operation in future low-carbon transportation systems. These results demonstrate a practical route to extending hydrogen utilization and supporting cleaner, more efficient engine operation in future low-carbon transportation systems.
Keywords
Hydrogen, Methanol, Injection Pressure, Knock, SI Engine, Dual Fuel
Published online 6/20/2026, 8 pages
Copyright © 2026 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA
Citation: S.T.P PURAYIL, SAB AL-OMARI, E. ELNAJJAR, Enhancing knock limit in hydrogen–gasoline dual fuel engine through methanol addition and injection pressure optimization, Materials Research Proceedings, Vol. 67, pp 47-54, 2026
DOI: https://doi.org/10.21741/9781644904176-7
The article was published as article 7 of the book Climate Action and Sustainability
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
References
[1] Li X, Zhen X, Wang Y, Liu D, Tian Z. The knock study of high compression ratio SI engine fueled with methanol in combination with different EGR rates. Fuel 2019;257:116098. https://doi.org/10.1016/j.fuel.2019.116098
[2] Yu X, Du Y, Sun P, Liu L, Wu H, Zuo X. Effects of hydrogen direct injection strategy on characteristics of lean-burn hydrogen-gasoline engines. Fuel 2017;208:602-11. https://doi.org/10.1016/j.fuel.2017.07.059
[3] D’andrea T, Henshaw PF, Ting D-K. The addition of hydrogen to a gasoline-fuelled SI engine. Int J Hydrogen Energy 2004;29:1541-52. https://doi.org/10.1016/j.ijhydene.2004.02.002
[4] Yu X, Guo Z, He L, Dong W, Sun P, Du Y, et al. Experimental study on lean-burn characteristics of an SI engine with hydrogen/gasoline combined injection and EGR. Int J Hydrogen Energy 2019;44:13988-98. https://doi.org/10.1016/j.ijhydene.2019.03.236
[5] Akif Ceviz M, Sen AK, Küleri AK, Volkan Öner İ. Engine performance, exhaust emissions, and cyclic variations in a lean-burn SI engine fueled by gasoline-hydrogen blends. Appl Therm Eng 2012;36:314-24. https://doi.org/10.1016/j.applthermaleng.2011.10.039
[6] Wang B, Wang H, Yang C, Hu D, Duan B, Wang Y. Effect of different ammonia/methanol ratios on engine combustion and emission performance. Appl Therm Eng 2024;236:121519. https://doi.org/10.1016/j.applthermaleng.2023.121519
[7] Sarıkoç S. Environmental and enviro-economic effect analysis of hydrogen-methanol-gasoline addition into an SI engine. Fuel 2023;344:128124. https://doi.org/10.1016/j.fuel.2023.128124
[8] Di Iorio S, Catapano F, Magno A, Sementa P, Vaglieco BM. The potential of ethanol/methanol blends as renewable fuels for DI SI engines. Energies 2023;16:2791. https://doi.org/10.3390/en16062791
[9] Purayil STP, Al-Omari SAB, Elnajjar E. Comparative Analysis of Knock Intensity in Spark Ignition Engines Using Gasoline and Hydrogen-Gasoline Blends. Int J Thermofluids 2025:101309. https://doi.org/10.1016/j.ijft.2025.101309
[10] Purayil STP, Al Martini E, Elsaid A, Khalil M, Zoghbour T, Seyam M, et al. Influence of steam induction on the performance and hydrogen knock limit of a hydrogen-gasoline spark ignition engine. Int J Thermofluids 2024:100933. https://doi.org/10.1016/j.ijft.2024.100933
[11] Purayil STP, Al-Omari SAB, Elnajjar E. Effect of Hydrogen Blending on the Combustion Performance, Emission, and Cycle-to-Cycle Variation Characteristics of a Single-Cylinder GDI Spark Ignition Dual-Fuel Engine. Int J Thermofluids 2023:100403. https://doi.org/10.1016/j.ijft.2023.100403
[12] Purayil STP, Al-Omari SAB, Elnajjar E. Experimental investigation of spark timing on extension of hydrogen knock limit and performance of a hydrogen-gasoline dual-fuel engine. Int J Hydrogen Energy 2024;49:910-22. https://doi.org/10.1016/j.ijhydene.2023.09.139
[13] Purayil STP, Al-Omari SAB, Elnajjar E. Experimental investigation on the influence of gasoline injection pressure on the hydrogen knock limit and performance of a hydrogen-gasoline dual fuel engine. Int J Hydrogen Energy 2024;81:1385-93. https://doi.org/10.1016/j.ijhydene.2024.07.281

