Electrochemical characterization of novel Cu51Zr30Hf14Ag5 metallic glass alloy composition

Electrochemical characterization of novel Cu51Zr30Hf14Ag5 metallic glass alloy composition

Shubhra SHITOLE, Abdel Hamid I. MOURAD, Asima Zahoor

Abstract. The development of novel, cytocompatibility metallic glasses is crucial for advancing next-generation biomedical implants. This research presents a comprehensive electrochemical investigation of the innovative Cu51Zr30Hf14Ag5 metallic glass, specifically evaluating its corrosion performance in alkaline environments to assess its potential for in vivo applications. The alloy was synthesized via melt-spinning, with its amorphous structure confirmed by X-ray diffraction. Its corrosion behaviour was rigorously analysed in NaOH solutions with varying pH using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Results demonstrated exceptional corrosion resistance in alkaline media. The formation of a stable passive film was validated by scanning electron microscopy and energy-dispersive spectroscopy. This study confirms the outstanding suitability of the Cu Zr Hf Ag system for biomedical applications, providing a foundational basis for its future use in implantology.

Keywords
Metallic Glasses, Aqueous Solution, Potentiodynamic Polarization, Electrochemical Impedance Spectroscopy, Corrosion Resistance

Published online 6/20/2026, 9 pages
Copyright © 2026 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Shubhra SHITOLE, Abdel Hamid I. MOURAD, Asima Zahoor, Electrochemical characterization of novel Cu51Zr30Hf14Ag5 metallic glass alloy composition, Materials Research Proceedings, Vol. 67, pp 324-332, 2026

DOI: https://doi.org/10.21741/9781644904176-44

The article was published as article 44 of the book Climate Action and Sustainability

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

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