Zinc Chloride Recovery for Synthesis of Porous Adsorbent from Lipid Condensate for Dye Removal

Zinc Chloride Recovery for Synthesis of Porous Adsorbent from Lipid Condensate for Dye Removal

Nurul Aishah ABDUL RAHIM, Muhammad Abbas AHMAD ZAINI, Sariah ABANG, Norlisa MILI

Abstract. Zinc chloride (ZnCl₂) is one of the most frequently used chemical activators for the synthesis of porous adsorbent. However, ZnCl₂ activator is constrained by the corrosive nature of zinc cations (Zn2+) and accumulation of chemical waste, posing a significant environmental concern. To address these issues, the potential of recycling the ZnCl₂ recovered from washing filtrate is explored as a resource utilization strategy. Lipid condensate, a by-product from the sterilization process in palm oil mill is proposed as a precursor for activation using the recovered ZnCl₂ washing filtrate. Preliminary insights suggest that the absorption performance of the absorbent produced with recovered ZnCl₂ may exhibit a comparable result to that prepared using fresh ZnCl₂. Nevertheless, further reuse of the activator beyond the first cycle of recovered ZnCl₂ may results in a significant decline of adsorption performance. This commentary highlights a practical approach for ZnCl₂ recovery aimed at reducing environmental burden while maximizing the utilization efficiency of ZnCl₂.

Keywords
Zinc Chloride Recovery, Porous Adsorbent, Lipid Condensate, Methylene Blue Adsorption, Chemical Activator, Wastewater Treatment

Published online 1/15/2026, 8 pages
Copyright © 2026 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Nurul Aishah ABDUL RAHIM, Muhammad Abbas AHMAD ZAINI, Sariah ABANG, Norlisa MILI, Zinc Chloride Recovery for Synthesis of Porous Adsorbent from Lipid Condensate for Dye Removal, Materials Research Proceedings, Vol. 59, pp 98-105, 2026

DOI: https://doi.org/10.21741/9781644903957-13

The article was published as article 13 of the book Separation Technology

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] N. Qurratu, ain Mohammad, N.A. Hazren Hamid, Palm Kernel Shell as Potential Adsorbent for Treatment and Decolorization of Palm Oil Mill Effluent (POME), 5 (2024) 557–562. https://doi.org/10.30880/peat.2024.05.01.059
[2] H. Kamyab, S. Chelliapan, M.F.M. Din, S. Rezania, T. Khademi, A. Kumar, Palm Oil Mill Effluent as an Environmental Pollutant, in: Palm Oil, InTech, 2018. https://doi.org/10.5772/intechopen.75811
[3] P. Nyawi, Biomass Palm oil as Renewable Energy, Malaysian Sustainable Palm Oil (2022).
[4] M.A. Bin Mohd Yusof, Y.J. Chan, C.H. Chong, C.L. Chew, Effects of operational processes and equipment in palm oil mills on characteristics of raw Palm Oil Mill Effluent (POME): A comparative study of four mills, Cleaner Waste Systems 5 (2023) 100–101. https://doi.org/10.1016/j.clwas.2023.100101
[5] N. Jusoh, M.B. Rosly, N. Othman, H.A. Rahman, N.F.M. Noah, R.N.R. Sulaiman, Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process, Environmental Science and Pollution Research 27 (2020) 23246–23257. https://doi.org/10.1007/s11356-020-07972-5
[6] M. Fan, Y. Shao, Y. Wang, J. Sun, H. He, Y. Jiang, S. Zhang, Y. Wang, X. Hu, Preparation of activated carbon with recycled ZnCl2 for maximizing utilization efficiency of the activating agent and minimizing generation of liquid waste, Chemical Engineering Journal 500 (2024) 157–278. https://doi.org/10.1016/j.cej.2024.157278
[7] Q.-F. Wu, F.-S. Zhang, A clean process for activator recovery during activated carbon production from waste biomass, Fuel 94 (2012) 426–432. https://doi.org/10.1016/j.fuel.2011.08.059
[8] M.A.A. Zaini, W.M. Tan, M.J. Kamaruddin, S.H.M. Setapar, M.A.C. Yunus, Microwave-Induced Zinc Chloride Activated Palm Kernel Shell for Dye Removal, 2014.
[9] C. Xia, S.Q. Shi, Self-activation for activated carbon from biomass: theory and parameters, Green Chemistry 18 (2016) 2063–2071. https://doi.org/10.1039/C5GC02152A
[10] Y. Gao, Q. Yue, B. Gao, A. Li, Insight into activated carbon from different kinds of chemical activating agents: A review, Science of The Total Environment 746 (2020) 141094. https://doi.org/10.1016/j.scitotenv.2020.141094
[11] J. Andas, N. Safinaz Naserun, Synthesis, Parameter Optimization and Characterization of ZnCl2 Activated Carbon Derived from Waste Tamarind Seed, 2025.
[12] B. Li, C. Li, D. Li, L. Zhang, S. Zhang, Z. Cui, D. Wang, Y. Tang, X. Hu, Activation of pine needles with zinc chloride: Evolution of functionalities and structures of activated carbon versus increasing temperature, Fuel Processing Technology 252 (2023) 107987. https://doi.org/10.1016/j.fuproc.2023.107987
[13] S.G. Herawan, M.S. Hadi, Md.R. Ayob, A. Putra, Characterization of Activated Carbons from Oil‐Palm Shell by CO 2 Activation with No Holding Carbonization Temperature, The Scientific World Journal 2013 (2013). https://doi.org/10.1155/2013/624865
[14] I. Yang, M. Jung, M.-S. Kim, D. Choi, J.C. Jung, Physical and chemical activation mechanisms of carbon materials based on the microdomain model, J Mater Chem A Mater 9 (2021) 9815–9825. https://doi.org/10.1039/D1TA00765C
[15] R. Farma, R.I. Julita, I. Apriyani, A. Awitdrus, E. Taer, ZnCl2-assisted synthesis of coffee bean bagasse-based activated carbon as a stable material for high-performance supercapacitors, Mater Today Proc 87 (2023) 25–31. https://doi.org/10.1016/j.matpr.2023.01.370
[16] B. Li, J. Hu, H. Xiong, Y. Xiao, Application and Properties of Microporous Carbons Activated by ZnCl 2 : Adsorption Behavior and Activation Mechanism, ACS Omega 5 (2020) 9398–9407. https://doi.org/10.1021/acsomega.0c00461
[17] M. Abbas Ahmad Zaini, T. Wee Meng, M. Johari Kamaruddin, Microwave-Induced Zinc Chloride Activated Palm Kernel Shell for Dye Removal, 2014.
[18] P.E. Hock, M.A.A. Zaini, Zinc chloride–activated glycerine pitch distillate for methylene blue removal—isotherm, kinetics and thermodynamics, Biomass Convers Biorefin 12 (2022) 2715–2726. https://doi.org/10.1007/s13399-020-00828-5
[19] F. Amran, T. Sarawanan, Y.K. Qi, A. Azmi, A. Arsad, M.A.A. Zaini, Coconut shell carbon via phosphoric acid activation for rhodamine B, malachite green, and methylene blue adsorption–equilibrium and kinetics, Int J Phytoremediation (2024). https://doi.org/10.1080/15226514.2024.2399062
[20] M.A. Akl, A.G. Mostafa, M. Al-Awadhi, W.S. Al-Harwi, A.S. El-Zeny, Zinc chloride activated carbon derived from date pits for efficient biosorption of brilliant green: adsorption characteristics and mechanism study, Appl Water Sci 13 (2023). https://doi.org/10.1007/s13201-023-02034-w