Laser texturing of 3D Copper current collector for ultrafast Zinc metal plating

Laser texturing of 3D Copper current collector for ultrafast Zinc metal plating

Vincenzina SICILIANI, Nassima YAMINI, Riccardo PELACCIA, Andrea PAOLELLA, Leonardo ORAZI

Abstract. Anode-free metal batteries with increased energy density hold promise for next-generation energy storage systems. However, the development of unwanted metal dendrites limits their practical application as electrodes. Zinc-ion batteries are promising since zinc is low-cost and allows the use of non-flammable aqueous electrolytes. 3D electrodes can reduce the current density per unit area and thus the dendrite formation. Quick laser texturing can selectively enhance zincphilicity within the grooves on Cu current collectors, increasing the charging rate. In this study, laser textures with different depths are performed on 100 µm Cu sheets electrode. Then, zinc metal is electrolytically deposited on the substrates and characterized by morphological and chemical (SEM/EDS) analysis. The half-cells with these collectors are tested in their functionality using a potentiostat. The textured current collectors will be evaluated as electrodes in Zn-ion batteries to achieve high charging rates.

Keywords
Laser Processes, Texture, Anode-Free Batteries

Published online 9/10/2025, 8 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Vincenzina SICILIANI, Nassima YAMINI, Riccardo PELACCIA, Andrea PAOLELLA, Leonardo ORAZI, Laser texturing of 3D Copper current collector for ultrafast Zinc metal plating, Materials Research Proceedings, Vol. 57, pp 286-293, 2025

DOI: https://doi.org/10.21741/9781644903735-33

The article was published as article 33 of the book Italian Manufacturing Association Conference

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] X. Zeng, J. Hao, Z. Wang, J. Mao, Z. Guo, Recent progress and perspectives on aqueous Zn-based rechargeable batteries with mild aqueous electrolytes, Energy Storage Materials 20 (2019) 410–437. https://doi.org/10.1016/j.ensm.2019.04.022
[2] D. Aurbach, Y. Talyosef, B. Markovsky, E. Markevich, E. Zinigrad, L. Asraf, J.S. Gnanaraj, H.-J. Kim, Design of electrolyte solutions for Li and Li-ion batteries: a review, Electrochimica Acta 50 (2004) 247–254. https://doi.org/10.1016/j.electacta.2004.01.090
[3] H. Sun, J. Zhu, D. Baumann, L. Peng, Y. Xu, I. Shakir, Y. Huang, X. Duan, Hierarchical 3D electrodes for electrochemical energy storage, Nat Rev Mater 4 (2019) 45–60. https://doi.org/10.1038/s41578-018-0069-9
[4] M. Kim, H. Bang, S. Hyun, S. Yi, C. Kim, Review on Ultrasonic and Laser Welding Technologies of Multi-Layer Thin Foils for the Lithium-Ion Pouch Cell Manufacturing, J Weld Join 41 (2023) 462–474. https://doi.org/10.5781/JWJ.2023.41.6.6
[5] E. Audouard, M. Fleureau, D. Pallarès, J.-M. Romano, F. Mermet, Characterization of batteries materials ablation by femtosecond pulses, Procedia CIRP 124 (2024) 57–60. https://doi.org/10.1016/j.procir.2024.08.070
[6] D. Neb, S. Kim, H. Clever, B. Dorn, A. Kampker, Current advances on laser drying of electrodes for lithium-ion battery cells, Procedia CIRP 107 (2022) 1577–1587. https://doi.org/10.1016/j.procir.2022.05.194
[7] T. Tsuda, N. Ando, S. Nakamura, Y. Ishihara, N. Hayashi, N. Soma, T. Gunji, T. Tanabe, T. Ohsaka, F. Matsumoto, Improvement of high-rate discharging performance of LiFePO4 cathodes by forming micrometer-sized through-holed electrode structures with a pico-second pulsed laser, Electrochimica Acta 296 (2019) 27–38. https://doi.org/10.1016/j.electacta.2018.11.014
[8] L. Hille, M.P. Noecker, B. Ko, J. Kriegler, J. Keilhofer, S. Stock, M.F. Zaeh, Integration of laser structuring into the electrode manufacturing process chain for lithium-ion batteries, Journal of Power Sources 556 (2023) 232478. https://doi.org/10.1016/j.jpowsour.2022.232478
[9] A. Sikora, L. Gemini, M. Faucon, G. Mincuzzi, Benefits of Femtosecond Laser 40 MHz Burst Mode for Li-Ion Battery Electrode Structuring, Materials 17 (2024) 881. https://doi.org/10.3390/ma17040881
[10] L. Romoli, A.H.A. Lutey, G. Lazzini, Laser texturing of Li-ion battery electrode current collectors for improved active layer interface adhesion, CIRP Annals 71 (2022) 481–484. https://doi.org/10.1016/j.cirp.2022.04.034
[11] E. Ravesio, A.H.A. Lutey, D. Versaci, L. Romoli, S. Bodoardo, Nanosecond pulsed laser texturing of Li-ion battery electrode current collectors: Electrochemical characterisation of cathode half-cells, Sustainable Materials and Technologies 38 (2023) e00751. https://doi.org/10.1016/j.susmat.2023.e00751
[12] Y. Wang, Z. Zhao, J. Zhong, T. Wang, L. Wang, H. Xu, J. Cao, J. Li, G. Zhang, H. Fei, J. Zhu, Hierarchically Micro/Nanostructured Current Collectors Induced by Ultrafast Femtosecond Laser Strategy for High‐Performance Lithium‐ion Batteries, Energy & Environ Materials 5 (2022) 969–976. https://doi.org/10.1002/eem2.12223
[13] P. Tallone, S. Spriano, D. Versaci, S. Ferraris, A. Tori, S. Bodoardo, Picosecond laser texturing of Al current collector to improve cycling performances and simplify recycling of Lithium-ion batteries, Surfaces and Interfaces 51 (2024) 104659. https://doi.org/10.1016/j.surfin.2024.104659
[14] E. Ravesio, G. Montinaro, G. Mincuzzi, M. Negozio, D. Versaci, V. Gartiser, A.H.A. Lutey, F. Bella, S. Bodoardo, Ultrashort pulsed laser texturing of current collector for Si/C Li-ion anodes: Characterization of electrochemical performance and evolution of interface morphology, Journal of Energy Storage 109 (2025) 115226. https://doi.org/10.1016/j.est.2024.115226