Investigation of glass-fiber reinforced polypropylene properties dependence on post-consumer recycled polypropylene content

Investigation of glass-fiber reinforced polypropylene properties dependence on post-consumer recycled polypropylene content

Anna BORTOLETTO, Matteo MICHELINI, Luca GAZZOLA, Adrian L. KELLY, Ben R. WHITESIDE, Marco SORGATO, Giovanni LUCCHETTA

Abstract. Polymer composites like glass fiber-reinforced polypropylene (GFRP) are widely used for their strength and lightweight properties, but their limited recyclability has raised significant sustainability challenges. This study explores the potential to improve the sustainability of GFRP composites by adding post-consumer recycled polypropylene (rPP). The impact of rPP and specifically of titanium dioxide (TiO₂), found in rPP as a residue of white inks, is evaluated. Two material sets were analyzed: one with varying rPP percentages and one with different TiO₂ levels intentionally added to virgin PP. Mechanical and rheological properties were evaluated through tensile and impact strength, DSC, TGA, SEM, and fiber length measurements. Results revealed TiO₂ contamination reduces fiber length, contributing to mechanical performance degradation. The findings highlight TiO₂’s significant role in recycled GFRP performance and emphasize improving recycling processes to enhance sustainability.

Keywords
Circular Economy, Sustainability, Fiber-Reinforced Plastic, Post-Consumer Recycling, Polypropylene

Published online 9/10/2025, 9 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: Anna BORTOLETTO, Matteo MICHELINI, Luca GAZZOLA, Adrian L. KELLY, Ben R. WHITESIDE, Marco SORGATO, Giovanni LUCCHETTA, Investigation of glass-fiber reinforced polypropylene properties dependence on post-consumer recycled polypropylene content, Materials Research Proceedings, Vol. 57, pp 2-10, 2025

DOI: https://doi.org/10.21741/9781644903735-1

The article was published as article 1 of the book Italian Manufacturing Association Conference

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] Suschem Materials Working Group, “Polymer Composites Circularity,” 2018. Accessed: Aug. 19, 2024. [Online]. Available: http: //www.suschem.org/publications
[2] M. Biron, “Thermoplastic Composites,” in Thermoplastics and Thermoplastic Composites, Elsevier, 2018, pp. 821–882. doi: 10.1016/B978-0-08-102501-7.00006-0
[3] D. García, I. Vegas, and I. Cacho, “Mechanical recycling of GFRP waste as short-fiber reinforcements in microconcrete,” Constr Build Mater, vol. 64, pp. 293–300, Aug. 2014. https://doi.org/10.1016/j.conbuildmat.2014.02.068
[4] H. Mohammadi et al., “Lightweight Glass Fiber-Reinforced Polymer Composite for Automotive Bumper Applications: A Review,” Polymers (Basel), vol. 15, no. 1, p. 193, Dec. 2022. https://doi.org/10.3390/polym15010193
[5] G. Xian et al., “Design, preparation and mechanical properties of novel glass fiber reinforced polypropylene bending bars,” Constr Build Mater, vol. 429, p. 136455, May 2024. https://doi.org/10.1016/j.conbuildmat.2024.136455
[6] F. Xie, “Sustainable polymer composites: functionality and applications,” Functional Composite Materials, vol. 2, no. 1, p. 15, Dec. 2021. https://doi.org/10.1186/s42252-021-00027-z
[7] S. Kolluru, A. Thakur, D. Tamakuwala, V. V. Kumar, S. Ramakrishna, and S. Chandran, “Sustainable recycling of polymers: a comprehensive review,” Jul. 01, 2024, Springer Science and Business Media Deutschland GmbH. doi: 10.1007/s00289-024-05195-z
[8] D. Borjan, Ž. Knez, and M. Knez, “Recycling of Carbon Fiber-Reinforced Composites—Difficulties and Future Perspectives,” Materials, vol. 14, no. 15, p. 4191, Jul. 2021. https://doi.org/10.3390/ma14154191
[9] D. P. Gravgaard, M. L. Henriksen, and M. Hinge, “Dissolution recycling for recovery of polypropylene and glass fibres,” J Mater Cycles Waste Manag, vol. 26, no. 2, pp. 961–969, Mar. 2024. https://doi.org/10.1007/s10163-023-01873-8
[10] S. Lu et al., “Effect of fiber content on mechanical properties of carbon fiber-reinforced polyether-ether-ketone composites prepared using screw extrusion-based online mixing 3D printing,” Addit Manuf, vol. 80, p. 103976, Jan. 2024. https://doi.org/10.1016/j.addma.2024.103976
[11] L. T. Drzal and M. Madhukar, “Fibre-matrix adhesion and its relationship to composite mechanical properties,” J Mater Sci, vol. 28, no. 3, pp. 569–610, 1993. https://doi.org/10.1007/BF01151234
[12] Á. Agüero et al., “Evaluation of Different Compatibilization Strategies to Improve the Performance of Injection-Molded Green Composite Pieces Made of Polylactide Reinforced with Short Flaxseed Fibers,” Polymers (Basel), vol. 12, no. 4, p. 821, Apr. 2020. https://doi.org/10.3390/polym12040821
[13] C. Cazan, A. Enesca, and L. Andronic, “Synergic Effect of TiO2 Filler on the Mechanical Properties of Polymer Nanocomposites,” Polymers (Basel), vol. 13, no. 12, p. 2017, Jun. 2021. https://doi.org/10.3390/polym13122017
[14] J. L. Thomason, “The influence of fibre length and concentration on the properties of glass fibre reinforced polypropylene: 5. Injection moulded long and short fibre PP,” Compos Part A Appl Sci Manuf, vol. 33, no. 12, pp. 1641–1652, Dec. 2002. https://doi.org/10.1016/S1359-835X(02)00179-3
[15] A. Ladhari, E. Kucukpinar, H. Stoll, and S. Sängerlaub, “Comparison of properties with relevance for the automotive sector in mechanically recycled and virgin polypropylene,” Recycling, vol. 6, no. 4, Dec. 2021. https://doi.org/10.3390/recycling6040076