Fundamentals and Applications of Nickel-based Superalloy
Uzma Hira, Iqra Ijaz
Nickel-based superalloys are essential for high-temperature applications due to their exceptional strength, corrosion, and oxidation resistance. Their microstructure, featuring a gamma matrix (γ), gamma-prime (γ’) precipitates, carbides and borides provide stability at elevated temperatures. Synthesis techniques include casting, powder metallurgy, and additive manufacturing each having its own specification. There have been several generations of nickel-based superalloys, and each new generation came up with increased creep resistance and working temperature. Superalloys based on nickel were first developed with an emphasis on solid-solution strengthening; later generations added intricate alloying elements to improve precipitation hardening. Because of their remarkable strength and stability at very high temperatures, these superalloys find extensive application in industrial gas turbines, aircraft, and power generation. Future advancements focus on additive manufacturing, nano engineering, and new alloy compositions to further enhance performance in extreme environments.
Keywords
Nickel-based Superalloys, Gamma Matrix, Gamma-Prime, Microstructure, Additive Manufacturing, Creep Resistance
Published online 9/10/2025, 27 pages
Citation: Uzma Hira, Iqra Ijaz, Fundamentals and Applications of Nickel-based Superalloy, Materials Research Foundations, Vol. 178, pp 41-67, 2025
DOI: https://doi.org/10.21741/9781644903698-3
Part of the book on Superalloys
References
[1] D. Satyanarayana, N. Satyanarayana, E. Prasad Nickel-based superalloys, Aerosp, Mater. Mater. Technol. 1 (2017) 199-228. https://doi.org/10.1007/978-981-10-2134-3_9
[2] C.T Sims, A contemporary view of nickel-base superalloys, JOM. (1966) 1119-1130. https://doi.org/10.1007/BF03378505
[3] S. Tin, T.M. Pollock, Nickel-based superalloys, in: T.I-P. Shih, V. Yang (Eds.), Turbine Aerodynamics, Heat Transfer, Materials and Mechanics, American Institute of Aeronautics and Astronautics, (2014) 423-466. https://doi.org/10.2514/5.9781624102660.0423.0466
[4] J.J Little, A field dislocation mechanics approach to emergent properties in two-phase nickel-based superalloys, University of Birmingham. (2020).
[5] H.A. Kishawy, A. Hosseini, Superalloys, Machining difficult-to-cut materials: basic principles and challenges, (2019) 97-137. https://doi.org/10.1007/978-3-319-95966-5_4
[6] C.T Sims, A history of superalloy metallurgy for superalloy metallurgists, Superalloys, (1984) 399-419. https://doi.org/10.7449/1984/Superalloys_1984_399_419
[7] R.C Reed, The superalloys: fundamentals and applications. Cambridge university press (2008)
[8] A. Kracke, and A. Allvac, Superalloys, the most successful alloy system of modern times-past, present and future, Proc. Int. Symp. on Superalloy, (2010). https://doi.org/10.1002/9781118495223.ch2
[9] A.F Giamei, Development of single crystal superalloys, a brief history, AM&P Technical Articles, (2013) 26-30. https://doi.org/10.31399/asm.amp.2013-09.p026
[10] A. Nowotnik, Development of nickel based superalloys for advanced turbine engines, Mater. Sci. forum. Trans Tech Publ. (2014). https://doi.org/10.4028/www.scientific.net/MSF.783-786.2491
[11] G.R Thellaputta, P.S. Chandra, and C. Rao, Machinability of nickel based superalloys, a review, Mater. Today Proc. 4 (2017) 3712-3721. https://doi.org/10.1016/j.matpr.2017.02.266
[12] R. Darolia, Development of strong, oxidation and corrosion resistant nickel-based superalloys, critical review of challenges, progress and prospect, Inter. Mater. Rev. 6 (2019) 355-380. https://doi.org/10.1080/09506608.2018.1516713
[13] A. Thakur, and S. Gangopadhyay, State-of-the-art in surface integrity in machining of nickel-based super alloys, IJMTM 100 (2016) 25-54. https://doi.org/10.1016/j.ijmachtools.2015.10.001
[14] A. Strondl, M. Palm, J. Gnauk, and G. Frommeyer, Microstructure and mechanical properties of nickel based superalloy IN718 produced by rapid prototyping with electron beam melting (EBM), Mater. Sci. Technol. 5 (2011) 876-883. https://doi.org/10.1179/026708309X12468927349451
[15] H.T. Lee, and W.H. Hou, Development of fine-grained structure and the mechanical properties of nickel-based Superalloy 718, Mater. Sci. Engr. A 555 (2012) 13-20. https://doi.org/10.1016/j.msea.2012.06.027
[16] Z. GaoLe, High-temperature mechanical properties of nickel-based superalloys manufactured by additive manufacturing, Mater. Sci. Technol. 14 (2020) 1523-1533. https://doi.org/10.1080/02670836.2020.1799137
[17] D. Zhang, Dynamic mechanical behavior of nickel-based superalloy metal rubber Mater. Des. 56 (2014) 69-77. https://doi.org/10.1016/j.matdes.2013.10.088
[18] E. Alabort, Grain boundary properties of a nickel-based superalloy: characterisation and modelling. Acta Mater. 151 (2018) 377-394. https://doi.org/10.1016/j.actamat.2018.03.059
[19] Y.T. Tang, A.J. Wilkinson, and R.C. Reed, Grain boundary serration in nickel-based superalloy inconel 600 generation and effects on mechanical behavior Metall. Mater. Trans A, 49 (2018) 4324-4342. https://doi.org/10.1007/s11661-018-4671-7
[20] M. Zieliñska, M. Yavorska, M. Porêba, and J. Sieniawski, Thermal properties of cast nickel based superalloys, Arch. Mater. Sci. Eng., 44 (2010) 35-38.
[21] M. Karunaratne, Modelling the coefficient of thermal expansion in Ni-based superalloys and bond coatings, J. Mater. Sci. 51 (2016) 4213-4226. https://doi.org/10.1007/s10853-015-9554-3
[22] H. Hamdi, H.R. Abedi, Thermal Stability of Ni-based Superalloys Fabricated Through Additive Manufacturing, A Review, JMR&T, (2024). https://doi.org/10.1016/j.jmrt.2024.04.161
[23] A. Tyagunov, O. Milder, and D. Tarasov, Application of artificial neural networks for prediction of nickel-based superalloys service properties based on the chemical composition, WSEAS Transactions on Environment and Development, 15 (2019) 113-119.
[24] J. Zuback, Impact of chemical composition on precipitate morphology in an additively manufactured nickel base superalloy, J. Alloys Compd. 798 (2019) 446-457. https://doi.org/10.1016/j.jallcom.2019.05.230
[25] D.K. Ganji, and G. Rajyalakshmi, Influence of alloying compositions on the properties of nickel-based superalloys, a review, Recent Advances in Mechanical Engineering, Select Proceedings of NCAME 2019, (2020) 537-555. https://doi.org/10.1007/978-981-15-1071-7_44
[26] B. Nithin, Effect of Cr addition on γ-γ′ cobalt-based Co-Mo-Al-Ta class of superalloys, a combined experimental and computational study, J. Mater. Sci. 52 (2017) 11036-11047. https://doi.org/10.1007/s10853-017-1159-6
[27] S.J. Park, Effects of Cr, W, and Mo on the high temperature oxidation of Ni-based superalloys, MDPI Mater. 12 (2019) 2934. https://doi.org/10.3390/ma12182934
[28] A. Jena, and M. Chaturvedi, The role of alloying elements in the design of nickel-base superalloys, J. Mater. Sci. 19 (1984) 3121-3139. https://doi.org/10.1007/BF00549796
[29] A. Chakraborty, Role of alloy composition on micro-cracking mechanisms in additively manufactured Ni-based superalloys, Acta Mater., 255 (2023) 119089. https://doi.org/10.1016/j.actamat.2023.119089
[30] P. Kontis, The effect of chromium and cobalt segregation at dislocations on nickel-based superalloys, Scr. Mater. 145 (2018) 76-80. https://doi.org/10.1016/j.scriptamat.2017.10.005
[31] L. Zhang, C.T. Peng, J. Shi, and R. Lu, Surface alloying of chromium/tungsten/stannum on pure nickel and theoretical analysis of strengthening mechanism, Appl. Surf. Sci., 532 (2020) 147477. https://doi.org/10.1016/j.apsusc.2020.147477
[32] A. Bauer, S. Neumeier, F. Pyczak, M. Göken, Creep strength and microstructure of polycrystalline γ′-strengthened cobalt-base superalloys, Superalloys 12 (2012) 695-703. https://doi.org/10.1002/9781118516430.ch77
[33] Y.C. Lin, and C.Y. Wang, Alloying-element dependence of structural, elastic and electronic properties of nickel-based superalloys: Influence of γ’volume fraction, J. Alloys Comp. 838 (2020) 155141. https://doi.org/10.1016/j.jallcom.2020.155141
[34] H. Mallikarjuna, N. Richards, W. Caley, Effect of alloying elements and microstructure on the cyclic oxidation performance of three nickel-based superalloys, Mater. 4 (2018) 487-499. https://doi.org/10.1016/j.mtla.2018.11.004
[35] Y. Chiu, and A. Ngan, Effects of boron doping on the grain-growth kinetics and mechanical properties of γ/γ′ nickel-aluminum alloys, Metall. Mater. Trans. A, 31 (2000) 3179-3186. https://doi.org/10.1007/s11661-000-0097-z
[36] Y. Chen, The strengthening effects and mechanisms of alloying elements on interfaces for multiphase Ni-based superalloys, A first-principles study, JMR&T, 23 (2023) 4802-4813. https://doi.org/10.1016/j.jmrt.2023.02.119
[37] Y. Murata, K. Suga, and N. Yukawa, Effect of transition elements on the properties of MC carbides in IN-100 nickel-based superalloy, J. Mater. Sci. 21 (1986) 3653-3660. https://doi.org/10.1007/BF00553814
[38] M. Bauccio, ASM metals reference book, ASM. Int. (1993).
[39] E. Caldwell, F. Fela, and G. Fuchs, The segregation of elements in high-refractory-content single-crystal nickel-based superalloys, JOM., 56 (2004) 44-48. https://doi.org/10.1007/s11837-004-0200-9
[40] Y. Ji, Effect of refractory elements M (= Re, W, Mo or Ta) on the diffusion properties of boron in nickel-based single crystal superalloys, Vacuum, 211 (2023) 111923. https://doi.org/10.1016/j.vacuum.2023.111923
[41] K. Povarova, Influence of rare-earth metals on the high-temperature strength of Ni 3 Al-based alloys, Russian Metall. (Metally), (2011) 47-54. https://doi.org/10.1134/S0036029511010137
[42] R.T. Holt, W. Wallace, Impurities and trace elements in nickel-base superalloys, Int. Met. Rev. 21 (1976) 1-24. https://doi.org/10.1179/095066076790136762
[43] Q. Zhang, Study of microstructure of nickel-based superalloys at high temperatures, Scr. Mater. 126 (2017) 55-57. https://doi.org/10.1016/j.scriptamat.2016.08.013
[44] S. Zhao, X. Xie, G.D. Smith, S.J. Patel, Microstructural stability and mechanical properties of a new nickel-based superalloy, Mater. Sci. Eng. A 355 (2003) 96-105. https://doi.org/10.1016/S0921-5093(03)00051-0
[45] S. Zhao, X. Xie, G.D. Smith, S.J. Patel, Gamma prime coarsening and age-hardening behaviors in a new nickel base superalloy, Mater. lett. 58 (2004) 1784-1787. https://doi.org/10.1016/j.matlet.2003.10.053
[46] A. Goodfellow, Gamma prime precipitate evolution during aging of a model nickel-based superalloy, Metall. Mater. Trans. A 49 (2018) 718-728. https://doi.org/10.1007/s11661-017-4336-y
[47] M.M. Barjesteh, S.M. Abbasi, K.Z. Madar, and K. Shirvani, The effect of heat treatment on characteristics of the gamma prime phase and hardness of the nickel-based superalloy Rene® 80, Mater. Chem. Phy. 227 (2019) 46-55. https://doi.org/10.1016/j.matchemphys.2019.01.038
[48] J. Singh, and K. Ravikanth, Roles of Refractory Solutes on the Stability of Carbide and Boride Phases in Nickel Superalloys, JPED. (2024) 1-25. https://doi.org/10.1007/s11669-024-01136-5
[49] L. Rakoczy, Analysis of γ′ precipitates, carbides and nano-borides in heat-treated Ni-based superalloy using SEM, STEM-EDX, and HRSTEM, Mater. 13 (2020) 4452. https://doi.org/10.3390/ma13194452
[50] Z. Asghary, S. Abbasi, M. Seifollahi, and M. Morakabati, Boron effect on phase transformation of σ and M23C6 in nimonic 105 superalloy, Mater. Res. Express, 6 (2019) 116529. https://doi.org/10.1088/2053-1591/ab446f
[51] J.E. Kanyo, S. Schafföner, R.S. Uwanyuze, and K.S. Leary, An overview of ceramic molds for investment casting of nickel superalloys, J. Eur. Ceram. Soc., 40 (2020) 4955-4973. https://doi.org/10.1016/j.jeurceramsoc.2020.07.013
[52] Q. Song, High-temperature flexural strength of aluminosilicate ceramic shells for the investment casting of nickel-based superalloy, IJMC. 18 (2024) 962-974. https://doi.org/10.1007/s40962-023-01061-2
[53] S. Jones, and C. Yuan, Advances in shell moulding for investment casting, J. Mater. Process.Technol. 135 (2003) 258-265. https://doi.org/10.1016/S0924-0136(02)00907-X
[54] H. A. Mehrabi, K. Salonitis, and M. Jolly, Sustainable Investment Casting. in 14th World Conference in Investment Casting, (2016).
[55] S. Pattnaik, D.B. Karunakar, and P.K. Jha, Developments in investment casting process, A review, J. Mater. Process.Technol. 212 (2012) 2332-2348. https://doi.org/10.1016/j.jmatprotec.2012.06.003
[56] E. Rzyankina, Numerical and experimental investigation of directional solidification in vacuum investment casting of superalloys, Cape Peninsula University of Technology, (2013).
[57] D. Szeliga, K. Kubiak, M. Motyka, and J. Sieniawski, Directional solidification of Ni-based superalloy castings: thermal analysis, Vacuum, 131 (2016) 327-342. https://doi.org/10.1016/j.vacuum.2016.07.009
[58] H.N. Mathur, Nucleation of recrystallisation in castings of single crystal Ni-based superalloys, Acta Mater. (2017) 112-123. https://doi.org/10.1016/j.actamat.2017.02.058
[59] J. Zhang , Recent progress in research and development of nickel-based single crystal superalloys, Acta. Metall. Sin. 129 (2023) 1109-1124.
[60] R. Jiang , Y. Song, and P. Reed, Fatigue crack growth mechanisms in powder metallurgy Ni-based superalloys, A review, Int. J. Fatigue, 141 (2020) 105887. https://doi.org/10.1016/j.ijfatigue.2020.105887
[61] C.L. Jia, C.C. Ge, and Q.Z. Yan, Innovative technologies for powder metallurgy-based disk superalloys: Progress and proposal, Chin. Phys. B 25(2016) 026103. https://doi.org/10.1088/1674-1056/25/2/026103
[62] M.M. Attallah, R. Jennings, X. Wang, and L.N. Carter, Additive manufacturing of Ni-based superalloys, the outstanding issues, MRS Bull. 41 (2016) 758-764. https://doi.org/10.1557/mrs.2016.211
[63] B. Graybill, Additive manufacturing of nickel-based superalloys, Int. MSEC, ASME. (2018) https://doi.org/10.1115/MSEC2018-6666
[64] M. Li , Metal binder jetting additive manufacturing, a literature review, J. Manuf. Sci. Eng., 142 (2020) 090801. https://doi.org/10.1115/1.4047430
[65] R. Wang, Microstructure characteristics of a René N5 Ni-based single-crystal superalloy prepared by laser-directed energy deposition, Addit. Manuf. 61 (2023) 103363. https://doi.org/10.1016/j.addma.2022.103363
[66] M.P. Haines, V.V. Rielli, S. Primig, and N. Haghdadi, Powder bed fusion additive manufacturing of Ni-based superalloys: a review of the main microstructural constituents and characterization techniques, J. Mater. Sci. 57 (2022) 14135-14187. https://doi.org/10.1007/s10853-022-07501-4
[67] A. Hariharan, Misorientation-dependent solute enrichment at interfaces and its contribution to defect formation mechanisms during laser additive manufacturing of superalloys, Phy. Rev. Mater. 3 (2019) 123602. https://doi.org/10.1103/PhysRevMaterials.3.123602
[68] N. Das, Advances in nickel-based cast superalloys, T. I. metals, 63 (2010) 265-274. https://doi.org/10.1007/s12666-010-0036-7
[69] E.W. Ross, and K.S. O’Hara, Rene N4: a first generation single crystal turbine airfoil alloy with improved oxidation resistance, low angle boundary strength and superior long time rupture strength, Superalloys, (1996) 19-25. https://doi.org/10.7449/1996/Superalloys_1996_19_25
[70] A. Cetel, and D. Duhl, Second generation nickel-base single crystal superalloy, Superalloys, (1988) 235-244. https://doi.org/10.7449/1988/Superalloys_1988_235_244
[71] K. Harris, Development of the rhenium containing superalloys CMSX-4 & CM 186 LC for single crystal blade and directionally solidified vane applications in advanced turbine engines, Superalloys (1992) 297. https://doi.org/10.7449/1992/Superalloys_1992_297_306
[72] A. Singh, Mechanisms related to different generations of γ′ precipitation during continuous cooling of a nickel base superalloy, Acta Mater, 61(2013) 280-293. https://doi.org/10.1016/j.actamat.2012.09.058
[73] T.M. Smith, Producing Next Generation Superalloys Through Advanced Characterization and Manufacturing Techniques. in Case Western Reserve University Seminar Series, (2020).
[74] S. Walston, Joint development of a fourth generation single crystal superalloy. 10th Int. Symp. on Superalloys, (2004). https://doi.org/10.7449/2004/Superalloys_2004_15_24
[75] N. Petrushin, E. Elyutin, E. Visik, and S. Golynets, Development of a single-crystal fifth-generation nickel superalloy, Russ. Metall. (Met.), 11 (2017) 936-947. https://doi.org/10.1134/S0036029517110118
[76] K. Kawagishi, Development of an oxidation-resistant high-strength sixth-generation single-crystal superalloy TMS-238, Superalloys, 9 (2012)189-195. https://doi.org/10.1002/9781118516430.ch21
[77] G. Wang, Process optimization and mechanical properties of oxide dispersion strengthened nickel-based superalloy by selective laser melting, Mater. Des. 188 (2020) 108418. https://doi.org/10.1016/j.matdes.2019.108418
[78] S. Pasebani, Oxide dispersion strengthened nickel based alloys via spark plasma sintering, Mater. Sci. Eng. A 630 (2015) 155-169. https://doi.org/10.1016/j.msea.2015.01.066
[79] S. Chikumba, and V.V. Rao. High entropy alloys, development and applications, ICLTET 2015, (2015).
[80] A. Yeh, Developing new type of high temperature alloys high entropy superalloys, Int. J. Metall. Mater. Eng. 1 (2015) 1-4. https://doi.org/10.15344/2455-2372/2015/107
[81] R. Smith, G. Lewi, and D. Yates, Development and application of nickel alloys in aerospace engineering, AEAT. 73 (2001) 138-147. https://doi.org/10.1108/00022660110694995
[82] M. Perrut, P. Caron, M. Thomas, A. Couret, High temperature materials for aerospace applications: Ni-based superalloys and γ-TiAl alloys, C. R. Phys. 19 (2018) 657-671. https://doi.org/10.1016/j.crhy.2018.10.002
[83] A. R. Jabalquinto, A. V. Tellez, P. Zambrano-Robledo, and B. B. Reyes, Feasibility of manufacturing combustion chambers for aeronautical use in Mexico, JART. 14 (2016) 167-172. https://doi.org/10.1016/j.jart.2016.05.003
[84] P.M. Sforza, Combustion Chambers for Air-Breathing Engines, in: Theory of Aerospace Propulsion, Butterworth-Heinemann, Boston. (2012) 127-159. https://doi.org/10.1016/B978-1-85617-912-6.00004-9
[85] A. Sato, Y.L. Chiu, R. Reed, Oxidation of nickel-based single-crystal superalloys for industrial gas turbine applications, Acta Mater. 59 (2011) 225-240. https://doi.org/10.1016/j.actamat.2010.09.027
[86] D. Klarstrom, L. Pike, V. Ishwar, Nickel-base alloy solutions for ultrasupercritical steam power plants, Procedia Eng. 55 (2013) 221-225. https://doi.org/10.1016/j.proeng.2013.03.246
[87] H. Alves, and M.S. Niederau, Successful applications of nickel alloys and high alloyed stainless steels in seawater service, (2008). https://doi.org/10.5006/C2008-08259
[88] M. N. Rao, Application of superalloys in petrochemical and marine sectors in India, Trans. Indian Inst. Metals 61 (2008) 87-91. https://doi.org/10.1007/s12666-008-0012-7
[89] M. Hardy, Solving recent challenges for wrought Ni-base superalloys, Metall. Mater. Trans. A. 51 (2020) 2626-2650. https://doi.org/10.1007/s11661-020-05773-6


