Correlation analysis of different solvent component in absorption-based acid gas removal unit

Correlation analysis of different solvent component in absorption-based acid gas removal unit

RAFI Jusar Wishnuwardana, MADIAH Binti Omar, HASLINDA Binti Zabiri, MOCHAMMAD Faqih, MUHAMMAD Hasif Bin Mohd Zaid, NURUL Izni Binti Ismail

Abstract. Natural gas is widely used in various applications including power generation and chemical industry. However, the natural gas from upstream contains several hazardous acid gases such as Hydrogen Sulfide (H2S) and Carbon Dioxide (CO2) which pose risks to both human health and the environment. Therefore, acid gas removal process is pivotal for purifying the natural gas before being delivered to the end-users. This paper aims to investigate the colleration between different solvent components used in absorption-based acid gas removal units. The analysis employs three correlation approaches: Pearson, Spearman, and Kendall. The data was simulated using a Hysys flowsheet by varying the type of solvent blends and compositions. The results indicate that the solvent blends MDEA+PZ and MDEA+DEA exhibit the highest correlation with CO2 removal, achieving a correlation value of -0.91. For H2S removal, the MDEA+SFL blend shows the highest correlation, with a value of -0.74. These findings suggest that specific solvent blending can significantly enhance the reduction of H2S and CO2 concentrations in sweet gas, underlining the importance of solvent selection in the acid gas removal process.

Keywords
Acid Gas Removal Unit, Solvent Component, Correlation Analysis

Published online 4/25/2025, 9 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: RAFI Jusar Wishnuwardana, MADIAH Binti Omar, HASLINDA Binti Zabiri, MOCHAMMAD Faqih, MUHAMMAD Hasif Bin Mohd Zaid, NURUL Izni Binti Ismail, Correlation analysis of different solvent component in absorption-based acid gas removal unit, Materials Research Proceedings, Vol. 53, pp 96-104, 2025

DOI: https://doi.org/10.21741/9781644903575-9

The article was published as article 9 of the book Decarbonization Technology

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] Carl Greenfield, “Natural Gas,” International Energy Agency, 2023. https://www.iea.org/energy-system/fossil-fuels/natural-gas#
[2] L. Addington and C. Ness, “An evaluation of general ‘rules of thumb’ in amine sweetening unit design and operation,” GPA Annu. Conv. Proc., vol. 1, pp. 119–135, 2010.
[3] S. Mokhatab and W. A. Poe, “Chapter 7 – Natural Gas Sweetening,” S. Mokhatab and W. A. B. T.-H. of N. G. T. and P. (Second E. Poe, Eds. Boston: Gulf Professional Publishing, 2012, pp. 253–290. doi: https://doi.org/10.1016/B978-0-12-386914-2.00007-8
[4] A. A. Abd and S. Z. Naji, “Comparison study of activators performance for MDEA solution of acid gases capturing from natural gas: Simulation-based on a real plant,” Environ. Technol. Innov., vol. 17, p. 100562, 2020. https://doi.org/10.1016/j.eti.2019.100562
[5] A. Pudi, M. Rezaei, V. Signorini, M. P. Andersson, M. G. Baschetti, and S. S. Mansouri, “Hydrogen sulfide capture and removal technologies: A comprehensive review of recent developments and emerging trends,” Sep. Purif. Technol., vol. 298, no. June, p. 121448, 2022. https://doi.org/10.1016/j.seppur.2022.121448
[6] A. Esmaeili, T. Yoon, T. A. Atsbha, and C. J. Lee, “Rate-based modeling and energy optimization of acid gas removal from natural gas stream using various amine solutions,” Process Saf. Environ. Prot., vol. 177, no. January, pp. 643–663, 2023. https://doi.org/10.1016/j.psep.2023.07.030
[7] I. I. I. Alkhatib, O. Khalifa, D. Bahamon, M. R. M. Abu-Zahra, and L. F. Vega, “Sustainability criteria as a game changer in the search for hybrid solvents for CO2 and H2S removal,” Sep. Purif. Technol., vol. 277, no. August, 2021. https://doi.org/10.1016/j.seppur.2021.119516
[8] A. S. Farooqi, R. M. Ramli, S. S. M. Lock, N. Hussein, A. S. Farooqi, and S. M. Wajahat, “Simulation of acid gas removal unit using DIPA+TEA amine solvent,” IOP Conf. Ser. Mater. Sci. Eng., vol. 1257, no. 1, p. 012033, 2022. https://doi.org/10.1088/1757-899x/1257/1/012033
[9] S. Y. Khan, M. Yusuf, and A. Malani, “Petroleum & Petrochemical Engineering Journal Selection of Amine in Natural Gas Sweetening Process for Acid Gases Removal : A Review of Recent Studies,” Pet. Petrochemical Eng. J., vol. 1, no. 3, pp. 1–7, 2017.
[10] A. Sharifi and E. Omidbakhsh Amiri, “Effect of the Tower Type on the Gas Sweetening Process,” Oil Gas Sci. Technol., vol. 72, no. 4, 2017. https://doi.org/10.2516/ogst/2017018
[11] U. Zahid, “Simulation of an acid gas removal unit using a DGA and MDEA blend instead of a single amine,” Chem. Prod. Process Model., vol. 15, no. 4, pp. 1–17, 2020. https://doi.org/10.1515/cppm-2019-0044
[12] U. Zahid, A. Sakheta, and C. J. Lee, “Techno-economic analysis of acid gas removal from associated and non-associated sour gas using amine blend,” Int. J. Greenh. Gas Control, vol. 98, no. November 2019, p. 103078, 2020. https://doi.org/10.1016/j.ijggc.2020.103078
[13] Y. C. Chang, R. B. Leron, and M. H. Li, “Equilibrium solubility of carbon dioxide in aqueous solutions of (diethylenetriamine + piperazine),” J. Chem. Thermodyn., vol. 64, pp. 106–113, 2013. https://doi.org/10.1016/j.jct.2013.05.005
[14] Albert W. Marshall, “Copulas, Marginals, and Joint Distributions,” Distrib. with Fixed Marginals Relat. Top., vol. 28, 1996, [Online]. Available: https://www.jstor.org/stable/4355894
[15] Nian Shong Chok, “Pearson’s versus Spearman’s and Kendall’s correlation coefficients for continuous data,” University of Pittsburgh, 2010. [Online]. Available: http://d-scholarship.pitt.edu/8056/1/Chokns_etd2010.pdf
[16] E. van den Heuvel and Z. Zhan, “Myths About Linear and Monotonic Associations: Pearson’s r, Spearman’s ρ, and Kendall’s τ,” Am. Stat., vol. 76, no. 1, pp. 44–52, 2022. https://doi.org/10.1080/00031305.2021.2004922
[17] P. Schober and L. A. Schwarte, “Correlation coefficients: Appropriate use and interpretation,” Anesth. Analg., vol. 126, no. 5, pp. 1763–1768, 2018. https://doi.org/10.1213/ANE.0000000000002864
[18] P. K. Pearson, F. G, and F. R. S. Received, “VII . Note on Regression and Inheritance in the Case of Two Parents,” Proceeding R. Soc. London, vol. 58, pp. 347–352, 1895.
[19] C. Spearman, “The Proof and Measurement of Association Between Two Things.,” Stud. Individ. Differ. search Intell., vol. 15, no. 1, pp. 45–58, 1904. https://doi.org/10.1037/11491-005
[20] J. D. Gibbons, Nonparametric measures of association. Sage, 1993.
[21] K. P. Kotz, Samuel, Tomasz Kozubowski, The Laplace distribution and generalizations: a revisit with applications to communications, economics, engineering, and finance. Springer Science & Business Media, 2012.
[22] M. G. Kendall, “A New Measure of Rank Correlation,” Biometrika, vol. 30, pp. 81–93, 1938. https://doi.org/10.1093/biomet/30.1-2.81