Lithium recovery from aqueous solution through adsorption using batch study

Lithium recovery from aqueous solution through adsorption using batch study

AL-DHAWİ Baker Nasser Saleh, MOHAMED KUTTY Shamsul Rahman, JAGABA Ahmad Husaini, ALMAHBASHİ Najib Mohammed Yahya, AL-YAARİ Abdullah

Abstract. Treating lithium in aqueous solutions through adsorption is crucial due to the rising demand for lithium in batteries and renewable energy. This method offers a cost-effective and efficient way to capture lithium ions. Effective treatment methods are essential to mitigating these environmental risks. To address this concern, separation technologies like adsorption have been utilized to remove lithium from solutions with minimal concentrations. This study specifically investigates the removal of residual lithium from a synthesized solution using aluminum hydroxide Al(OH)3 as the adsorbent. The research examines the impact of adsorbent dosage, lithium concentration, and pH on residual lithium removal. Results underscore the substantial influence of pH on residual lithium efficiency, with optimal removal observed at pH 4.5, an adsorbent dosage of 1150 mg/L, and a lithium concentration of 1150 mg/L, achieving an 89% removal rate. The utilization of Al(OH)3for lithium adsorption has been demonstrated as an efficient technique for for recovering lithium from synthesis solutions. The process followed a pseudo-first-order kinetic model (R² = 0.917) and fit the Langmuir isotherm model (R² = 0.91). These findings contribute to a better understanding of Al(OH)3 adsorption behavior and provide perspectives on the most favorable operational parameters for effective lithium recovery.

Keywords
Lithium, Batch Study, Adsorption, Kinetic, Isotherm

Published online 4/25/2025, 7 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: AL-DHAWİ Baker Nasser Saleh, MOHAMED KUTTY Shamsul Rahman, JAGABA Ahmad Husaini, ALMAHBASHİ Najib Mohammed Yahya, AL-YAARİ Abdullah, Lithium recovery from aqueous solution through adsorption using batch study, Materials Research Proceedings, Vol. 53, pp 74-80, 2025

DOI: https://doi.org/10.21741/9781644903575-6

The article was published as article 6 of the book Decarbonization Technology

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

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