Influence of Tween 65 on Carbon dioxide Hydrate System
MANJUSHA Anipeddi, LAL Bhajan, SOW MUN Serene Lock, DESHANNAVAR Umesh
Abstract. The effect of Tween 65 promoter on the kinetics for the hydrate of CO2 to form was being experimentally evaluated . The experiments were conducted using constant cooling method in RAMAN reactor at formation pressure of 4 MPa and 275.15 K. The experiments were performed at 500,1000,1500 and 2000 ppm concentration of Tween 65. The results showed that the induction time for 500 ppm was 3.23 which reduced to 3.18 with increase in concentration of promoter to 1000 ppm. Furthermore the CO2 to hydrate conversion was found to be 58.44 for 2000 ppm and average gas uptake was more for 1500 ppm concentration. The results in this work show that Tween 65 is an effective kinetic promoter.
Keywords
CO2hydrate, Promoter, Concentration, Tween 65, Kinetics
Published online 4/25/2025, 7 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA
Citation: MANJUSHA Anipeddi, LAL Bhajan, SOW MUN Serene Lock, DESHANNAVAR Umesh, Influence of Tween 65 on Carbon dioxide Hydrate System, Materials Research Proceedings, Vol. 53, pp 43-49, 2025
DOI: https://doi.org/10.21741/9781644903575-3
The article was published as article 3 of the book Decarbonization Technology
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
References
[1] Nesterov, A., Journal, A. R.-C. E. & 2019, undefined. New combination of thermodynamic and kinetic promoters to enhance carbon dioxide hydrate formation under static conditions. Elsevier. https://doi.org/10.1016/j.cej.2019.122165
[2] Nasir, Q., Suleman, H., and, Y. E.-J. of N. G. S. & 2020, undefined. A review on the role and impact of various additives as promoters/inhibitors for gas hydrate formation. Elsevier. https://doi.org/10.1016/j.jngse.2020.103211
[3] Prasad, P., Engineering, B. K.-J. of N. G. S. and & 2018, undefined. Are the amino acids thermodynamic inhibitors or kinetic promoters for carbon dioxide hydrates? Elsevier. https://doi.org/10.1016/j.jngse.2018.02.001
[4] Karaaslan, U. & Parlaktuna, M. Surfactants as hydrate promoters? Energy and Fuels 14, 1103-1107 (2000). https://doi.org/10.1021/ef000069s
[5] Li, Y., Gambelli, A., Rossi, F., Equilibria, S. M.-F. P. & 2021, undefined. Effect of promoters on CO2 hydrate formation: Thermodynamic assessment and microscale Raman spectroscopy/hydrate crystal morphology characterization. Elsevier. https://doi.org/10.1016/j.fluid.2021.113218
[6] Karaaslan, U., Fuels, M. P.-E. & & 2000, undefined. Surfactants as hydrate promoters? ACS Publications 34, 4397-4400 (2000).
[7] Arora, A., Cameotra, S., Kumar, R., reports, C. B.-S. & 2016, undefined. Biosurfactant as a promoter of methane hydrate formation: thermodynamic and kinetic studies. nature.com. https://doi.org/10.1038/srep20893
[8] Partoon, B., Engineering, J. J.-J. of C. & & 2013, undefined. Effect of mixed thermodynamic and kinetic hydrate promoters on methane hydrate phase boundary and formation kinetics. ACS Publications 58, 501-509 (2013). https://doi.org/10.1021/je301153t
[9] Kumar, A., Bhattacharjee, G., … V. B.-J. of environmental & 2016, undefined. Influence of kinetic and thermodynamic promoters on post-combustion carbon dioxide capture through gas hydrate crystallization. Elsevier. https://doi.org/10.1016/j.jece.2016.03.021
[10] Park, S. et al. Hydrate-based pre-combustion capture of carbon dioxide in the presence of a thermodynamic promoter and porous silica gels. Elsevier.
[11] Majid, A., Worley, J., Fuels, C. K.-E. & & 2021, undefined. Thermodynamic and kinetic promoters for gas hydrate technological applications. ACS Publications 35, 19288-19301 (2021). https://doi.org/10.1021/acs.energyfuels.1c02786
[12] Daraboina, N. & Von Solms, N. The combined effect of thermodynamic promoters tetrahydrofuran and cyclopentane on the kinetics of flue gas hydrate formation. J Chem Eng Data 60, 247-251 (2015). https://doi.org/10.1021/je500529w
[13] Bavoh, C. B., Lal, B. & Keong, L. K. Introduction to Gas Hydrates. Green Energy and Technology 1-25 (2020) doi:10.1007/978-3-030-30750-9_1. https://doi.org/10.1007/978-3-030-30750-9_1
[14] Wu, W. et al. Application of monocyclic compounds as natural gas hydrate promoters: A review. Elsevier.
[15] Herslund, P., Daraboina, N., Thomsen, K., J. A.-F. P. & 2014, undefined. Measuring and modelling of the combined thermodynamic promoting effect of tetrahydrofuran and cyclopentane on carbon dioxide hydrates. Elsevier. https://doi.org/10.1016/j.fluid.2014.08.015
[16] Lal, B. & Nashed, O. Chemical additives for gas hydrates. (2019). https://doi.org/10.1007/978-3-030-30750-9
[17] Mech, D., Gupta, P., and, J. S.-J. of N. G. S. & 2016, undefined. Kinetics of methane hydrate formation in an aqueous solution of thermodynamic promoters (THF and TBAB) with and without kinetic promoter (SDS). Elsevier. https://doi.org/10.1016/j.jngse.2016.06.013
[18] Nashed, O., Partoon, B., Lal, B., … K. S.-J. of N. G. & 2018, undefined. Review the impact of nanoparticles on the thermodynamics and kinetics of gas hydrate formation. Elsevier. https://doi.org/10.1016/j.jngse.2018.05.022
[19] Daraboina, N., Engineering, N. von S.-J. of C. & & 2015, undefined. The combined effect of thermodynamic promoters tetrahydrofuran and cyclopentane on the kinetics of flue gas hydrate formation. ACS Publications. https://doi.org/10.1021/je500529w
[20] Amirun Nissa Rehman, Rajashekhar Pendyala, Bhajan Lal. “Effect of brine on the kinetics of Carbon dioxide hydrate formation and dissociation in porous media”, Materials Today: Proceedings, 2021 https://doi.org/10.1016/j.matpr.2021.04.024
[21] Amirun Nissa Rehman, Cornelius B. Bavoh, Bhajan Lal, Khalik M. Sabil, Jitendra S. Sangwai. ” Insights on CO Hydrate Formation and Dissociation Kinetics of Amino Acids in a Brine Solution “, Industrial & Engineering Chemistry Research, 2022 [22] Lee, K.; Lee, S. H.; Lee, W. Stochastic Nature of Carbon Dioxide Hydrate Induction Times in Na-Montmorillonite and Marine Sediment Suspensions. Int. J. Greenhouse Gas Control 2013, 14, 15- 24 https://doi.org/10.1016/j.ijggc.2013.01.001
[23] D. Sun, P. Englezos, Storage of CO2 in a partially water saturated porous medium at gas hydrate formation conditions, Int. J. Greenh. Gas Control. 25 (2014) https://doi.org/10.1016/j.ijggc.2014.03.008
[24] Smith, J. M. Introduction to Chemical Engineering Thermodynamics. J. Chem. Educ. 1950, 27, 584, DOI: 10.1021/ed027p584.3 There is no corresponding record for this reference. https://doi.org/10.1021/ed027p584.3
[25] Bhattacharjee, Gaurav; Kumar, Asheesh; Sakpal, Tushar; Kumar, Rajnish ACS Sustainable Chemistry & Engineering (2015), 3 (6), 1205-1214CODEN: ASCECG; ISSN:2168-0485. (American Chemical Society) https://doi.org/10.1021/acssuschemeng.5b00171
[26] Sun, D.; Englezos, P. Storage of CO2 in a partially water saturated porous medium at gas hydrate formation conditions. Int. J. Greenhouse Gas Control 2014, 25, 1- 8 https://doi.org/10.1016/j.ijggc.2014.03.008
[27] Anderson, G. K. Enthalpy of Dissociation and Hydration Number of Carbon Dioxide Hydrate from the Clapeyron Equation. J. Chem. Thermodynamic. 2003, 35,1171-1183 https://doi.org/10.1016/S0021-9614(03)00093-4
