Removal of phosphate from aqueous solution through synergistic extractive extraction
Izzat Naim Shamsul Kahar, Shuhada A. Idrus-Saidi, Musyazrina Alya Musa, Norasikin Othman, Aishah Rosli
Abstract. This study presents the utilization of a synergistic extractant for phosphate removal from an aqueous solution using extractive extraction. In this study, the synergistic extractant for phosphate removal was formulated and its concentration was investigated. Additionally, the stripping agent concentration was studied to strip phosphate from its loaded organic phase. The extraction and stripping mechanisms of phosphate were also examined. The results show that more than 97% of phosphate was effectively extracted using a synergistic extractant of 0.1 M TOMAC/0.002 M octanol dissolved in a green diluent mixture of palm oil and sunflower oil. The synergistic coefficient of the extraction is 36.76. Meanwhile an approximately 73% of phosphate was stripped using 0.5 M NaOH. Therefore, the developed formulation of synergistic extraction demonstrates a promise for removing phosphate from agricultural effluents.
Keywords
Phosphate, Removal, Synergistic Extractive Extraction, Green Diluent
Published online 4/25/2025, 10 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA
Citation: Izzat Naim Shamsul Kahar, Shuhada A. Idrus-Saidi, Musyazrina Alya Musa, Norasikin Othman, Aishah Rosli, Removal of phosphate from aqueous solution through synergistic extractive extraction, Materials Research Proceedings, Vol. 53, pp 136-145, 2025
DOI: https://doi.org/10.21741/9781644903575-13
The article was published as article 13 of the book Decarbonization Technology
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
References
[1] S.P. Hong, H. Yoon, J. Lee, C. Kim, S. Kim, J. Lee, C. Lee, J. Yoon, Selective phosphate removal using layered double hydroxide/reduced graphene oxide (LDH/rGO) composite electrode in capacitive deionization, J. Colloid Interface Sci. 564 (2020) 1–7. https://doi.org/10.1016/j.jcis.2019.12.068
[2] N. Che, J. Qu, J. Wang, N. Liu, C. Li, Y. Liu, Adsorption of phosphate onto agricultural waste biochars with ferrite/manganese modified-ball-milled treatment and its reuse in saline soil, Sci. Total Environ. 915 (2024) 169841. https://doi.org/10.1016/j.scitotenv.2023.169841
[3] N.F.M. Noah, N. Othman, Y. V Arumugam, I.N.S. Kahar, S.S. Suliman, Extractive extraction for platinum recovery using synergistic organic formulation of Aliquat 336 / TBP mixtures, Mater. Today Proc. 96 (2024) 17–22. https://doi.org/10.1016/j.matpr.2023.08.156
[4] F.M. Antony, K.L. Wasewar, The Sustainable Approach of Process Intensification in Biorefinery Through Reactive Extraction Coupled with Regeneration for Recovery of Protocatechuic Acid, Appl. Biochem. Biotechnol. (2023) 1570–1591. https://doi.org/10.1007/s12010-023-04659-8
[5] M.E. Marti, H. Zeidan, Using eco-friendly alternatives for the recovery of pyruvic acid by reactive extraction, Sep. Purif. Technol. 312 (2023) 123309. https://doi.org/10.1016/j.seppur.2023.123309
[6] S. Ilyas, R.R. Srivastava, H. Kim, Liquid-liquid extraction of phosphorus from sulfuric acid solution using benzyl dimethyl amine, Int. J. Miner. Metall. Mater. 28 (2021) 367–372. https://doi.org/10.1007/s12613-020-2151-8
[7] R.N.R. Sulaiman, A. Rosli, N. Othman, M.A.A. Zaini, Novel Extraction of Phosphorus using Interaction of Tricaprylylmethylammonium Chloride (TOMAC) with Biodegradable Mixture of Vegetable Oils, Malaysian J. Fundam. Appl. Sci. 19 (2023) 769–780. https://doi.org/10.11113/mjfas.v19n5.3053
[8] G. Zhang, D. Chen, W. Zhao, H. Zhao, L. Wang, W. Wang, T. Qi, A novel D2EHPA-based synergistic extraction system for the recovery of chromium (III), Chem. Eng. J. 302 (2016) 233–238. https://doi.org/10.1016/j.cej.2016.05.063
[9] T.H. Nguyen, M.S. Lee, A review on the separation of lithium ion from leach liquors of primary and secondary resources by solvent extraction with commercial extractants, Processes. 6 (2018) 1–15. https://doi.org/10.3390/pr6050055
[10] H. Wang, S. Kuang, W. Liao, Synergistic extraction and separation of thorium from rare earths in chloride media using mixture of Cextrant 230 and Cyanex 923, J. Rare Earths. 42 (2024) 759–767. https://doi.org/10.1016/j.jre.2023.04.016
[11] A. Jackson, M. Nilsson, Synergism and Aggregation in Multi-Extractant Solvent Extraction Systems, Solvent Extr. Ion Exch. 37 (2019) 269–283. https://doi.org/10.1080/07366299.2019.1639367
[12] I.N.S. Kahar, N. Othman, N.F.M. Noah, S.S. Suliman, Recovery of copper and silver from industrial e‑waste leached solutions using sustainable liquid membrane technology : a review, Environ. Sci. Pollut. Res. 30 (2023) 66445–66472. https://doi.org/10.1007/s11356-023-26951-0
[13] H.A. Rahman, N. Jusoh, N. Othman, M.B. Rosly, R.N.R. Sulaiman, N.F.M. Noah, Green formulation for synthetic dye extraction using synergistic mixture of acid-base extractant, Sep. Purif. Technol. 209 (2019) 293–300. https://doi.org/10.1016/j.seppur.2018.07.053
[14] N. Jusoh, N. Othman, N.M. Amin, R.N.R. Sulaiman, N.F.M. Noah, S. Nurulashikin, M.A.A. Zaini, Synergistic Formulation for Turquoise Blue Dye Extraction Using Mixed Trioctylamine/Cyanex 302 in Liquid-Liquid Extraction System, 200 (2021) 1–9. https://doi.org/10.2991/aer.k.201229.001
[15] D. Caşcaval, A.I. Galaction, L. Kloetzer, Synergic Extraction of Folic Acid with Di(2-ethylhexyl) Phosphoric Acid and Amberlite LA-2, Sep. Sci. Technol. 47 (2012) 834–841. https://doi.org/10.1080/01496395.2011.630056
[16] A.I. Galaction, M. Poştaru, A.S. Bompa, D. Caşcaval, Synergic extraction of pantothenic acid with two different extractants, Brazilian J. Chem. Eng. 33 (2016) 1031–1040. https://doi.org/10.1590/0104-6632.20160334s20150265
[17] C. Homsirikamol, N. Sunsandee, U. Pancharoen, K. Nootong, Synergistic extraction of amoxicillin from aqueous solution by using binary mixtures of Aliquat 336, D2EHPA and TBP, Sep. Purif. Technol. 162 (2016) 30–36. https://doi.org/10.1016/j.seppur.2016.02.003
[18] A. Kumar, A. Thakur, Reactive extraction of lactic acid using environmentally benign green solvents and a synergistic mixture of extractants, Sci. Iran. 26 (2019) 3456–3467. https://doi.org/10.24200/sci.2019.52233.2610
[19] Y. Wang, Q. Zhang, M. Liu, H. Liu, Y. Chen, X. Hu, Simulation and dynamic control of removal phenols from coal gasification wastewater by synergistic extraction, Sep. Purif. Technol. 285 (2022) 120347. https://doi.org/10.1016/j.seppur.2021.120347
[20] J.M. Racicot, T.L. Mako, A. Olivelli, M. Levine, A paper-based device for ultrasensitive, colorimetric phosphate detection in seawater, Sensors. 20 (2020) 2776.
[21] R.N.R. Sulaiman, H.A. Rahman, N. Othman, M.B. Rosly, N. Jusoh, N.F.M. Noah, Extraction of reactive dye via synergistic Aliquat 336/D2EHPA using emulsion liquid membrane system, Korean J. Chem. Eng. 37 (2020) 141–150. https://doi.org/10.1007/s11814-019-0418-4
[22] L. Kloetzer, R.A. Ilica, D. Cascaval, A.I. Galaction, Separation of fumaric acid by amine extraction without and with 1-octanol as phase modifier, Sep. Purif. Technol. 227 (2019) 115724. https://doi.org/10.1016/j.seppur.2019.115724
[23] N. Jusoh, M.B. Rosly, N. Othman, H.A. Rahman, N.F.M. Noah, R.N.R. Sulaiman, Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process, Environ. Sci. Pollut. Res. 27 (2020) 23246–23257. https://doi.org/10.1007/s11356-020-07972-5
[24] A. Swarnkar, A. Keshav, A.B. Soni, Recovery of Methacrylic Acid from the Aqueous Phase Using Trioctylmethylammonium Chloride (TOMAC) in Different Diluents, J. Chem. Eng. Data. 61 (2016) 1412–1420. https://doi.org/10.1021/acs.jced.5b00553
[25] R.G. Lazar, A.C. Blaga, E.N. Dragoi, A.I. Galaction, D. Cascaval, Application of reactive extraction for the separation of pseudomonic acids: Influencing factors, interfacial mechanism, and process modelling, Can. J. Chem. Eng. 100 (2022) S246–S257. https://doi.org/10.1002/cjce.24124
[26] D. Luo, J. Huang, Y. Zhang, H. Liu, P. Hu, Efficient and environment-friendly vanadium (V) extraction from vanadium shale leachate using tri-n-octylmethylammonium chloride, Sep. Purif. Technol. 237 (2020) 116482. https://doi.org/10.1016/j.seppur.2019.116482
[27] M.B. Rosly, N. Jusoh, N. Othman, H.A. Rahman, N.F.M. Noah, R.N.R. Sulaiman, Synergism of Aliquat336-D2EHPA as carrier on the selectivity of organic compound dyes extraction via emulsion liquid membrane process, Sep. Purif. Technol. 239 (2020) 116527. https://doi.org/10.1016/j.seppur.2020.116527
[28] N.C. Firsta, R.D. Mentari, E.S. Salafiah, T. Estiasih, Preparation of unsaponifiable fraction from crude palm oil: A short review, IOP Conf. Ser. Earth Environ. Sci. 475 (2020). https://doi.org/10.1088/1755-1315/475/1/012032