Characterization and workability of rice husk ash-calcium nitrate blended cement concrete
Akeem Ayinde RAHEEM, Isaiah Oluwafemi OGUNTOLA, Favour Wuraola KOLAWOLE, Oludayo Ajani AKINTOLA
Abstract. Blended cement is a type of cement that is produced by blending different supplementary cementitious materials (SCMs) with Portland cement clinker. Ash from agricultural residues which are typically classified as waste, is found to exhibit pozzolanic qualities and are being employed in place of cement in the search for an alternative binder. This study investigates the characterization and workability of Rice Husk Ash (RHA)-calcium nitrate (CN) blended cement concrete. Ordinary Portland cement (OPC), RHA and CN were characterized using X-ray fluorescence analysis. Concrete mixes using a fixed content of 15% RHA as replacement for cement and 1, 2, 3, 4, and 5% CN as substitute by weight of OPC with mix ratio 1:2:4 was produced. The water-to-cement ratio of 0.6 was adopted. Concrete without RHA and CN serves as control 1, while concrete with only RHA serves as control 2 mix. Workability (slump and compacting) and setting times of the concrete were determined. RHA was found to be a pozzolanic material because the sum of SiO2, AlO3, and Fe2O3 was 75.36% ≥ 70%. The CaO content present in CN, OPC and RHA were 81.95, 68.76 and 5.62%, respectively. The slump and compacting factor ranged from 14 to 34 mm and 0.72 to 0.84 mm, respectively. The initial and final setting time ranged from 129 to 231 minutes and 221 to 379 minutes, respectively. The addition of CN improved the workability and setting times of fresh concrete made with RHA-CN.
Keywords
Rice Hush Ash, Calcium Nitrate, Supplementary Cementitious Materials, Blended Cement, Workability
Published online 3/25/2025, 10 pages
Copyright © 2025 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA
Citation: Akeem Ayinde RAHEEM, Isaiah Oluwafemi OGUNTOLA, Favour Wuraola KOLAWOLE, Oludayo Ajani AKINTOLA, Characterization and workability of rice husk ash-calcium nitrate blended cement concrete, Materials Research Proceedings, Vol. 51, pp 28-38, 2025
DOI: https://doi.org/10.21741/9781644903537-4
The article was published as article 4 of the book Advances in Cement and Concrete
Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.
References
[1] Ahmed, A., Hyndman, F., Kamau, J. and Fitriani, H. Rice husk ash as a cement replacement in high strength sustainable concrete. Mater Sci Forum. 10,7 (2020) 90–98.
[2] Ali, T., Saand, A., Bangwar, D., Buller, A., and Ahmed, Z. Mechanical and durability properties of aerated concrete incorporating rice husk ash (RHA) as partial replacement of cement. Crystals.11 (2021) 604. https://doi.org/10.3390/cryst11060604
[3] American Society for Testing and Materials. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM C618 (2021). Retrieved from: https://www.astm.org/Standards/C618
[4] Arum, C., Ikumapayi, C. M. and Aralepo, G. O. Ashes of biogenic wastes: Pozzolanicity, prospects for use, and effects on some engineering properties of concrete. (2013). Retrieved from: https://scite.ai/reports/10.4236/msa
[5] ASTM C33/C33M. Standard specification for concrete aggregates. ASTM International; (2023).
[6] ASTM C618-12. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM International, West Conshohocken, PA; (2012). https://doi.org/10.1520/C0618
[7] ASTM D2487. Standard practice for classification of soils for engineering purposes. ASTM International, West Conshohocken, PA; (2011).
[8] Bowles, J. E. Engineering properties of soils and their measurements. 4th ed. New York: McGraw-Hill (1992).
[9] British Standards Institution. Methods of testing cement: Determination of setting times and soundness. BS EN 196: Part 3. London: BSI (2005).
[10] BS EN ISO 10545. Ceramic tiles. Determination of water absorption, apparent porosity, apparent relative density, and bulk-density. British Standards Institution, London (1997).
[11] Faria, K. C. P., Gurgel, R. F. and Holanda, J. N. F. Recycling of sugarcane bagasse ash waste in the production of clay bricks. J Environ Manage. 101 (2012) 7-12. https://doi.org/10.1016/j.jenvman
[12] Ganesan, K., Rajagopal, K. and Thangavel, K. Rice husk ash blended cement: Assessment of optimal level of replacement for strength and permeability properties of concrete. Constr Build Mater.22,8 (2008) 1675-1683. https://doi.org/10.1016/j.conbuildmat
[13] Givi, A. N., Rashid, S. A., Aziz, F. N. A. and Salleh, M. A. M. Contribution of rice husk ash to the properties of mortar and concrete: A review. Constr Build Mater. 24,11 (2010) 1231-1245. https://doi.org/10.1016/j.conbuildmat
[14] Kazmi, S. M. S, Abbas, S., Munir, M. J, and Khitab, A. Exploratory study on the effect of waste rice husk and sugarcane bagasse ashes in burnt clay bricks. J Build Eng. 7 (2016) 372-378. https://doi.org/10.1016/j.jobe
[15] Nair, D.G, Jagadish, K. S, Fraaij, ALA. Reactive pozzolanas from rice husk ash: An alternative to cement for rural housing. Cem Concr Res. 36,6 (2006) 1062-1071. https://doi.org/10.1016/j.cemconres
[16] Neville, A. M and Brooks, J. J. Concrete technology. Pearson Education; (2010).
[17] Neville, A. M. Properties of concrete. 5th ed. Pearson Education Limited; (2011).
[18] Ogunbode, E. B. and Hassan, I. O. Effect of addition of calcium nitrate on selected properties of concrete containing volcanic ash. Leonardo Electron J Pract Technol. 19 (2011) 29-38.
[19] Okonkwo, C. E. and Igwe, C. C. The potential of rice husk ash as a supplementary cementitious material in Nigeria: A review. J Constr Build Mater. 46 (2021) 110-122.
[20] Oriola K. O., Raheem A. A., Kareem, M. A. and Abdulwahab, R. Assessment of workability and compressive strength of rice husk ash-blended palm kernel shell. J Civil Environ Stud. 7,1 (2021). https://doi.org/10.36108/
[21] Raheem, A. A. and Ikotun, B. D. Incorporation of agricultural residues as partial substitution for cement in concrete and mortar: A review. J Build Eng. 31 (2020). https://10.1016/j.101428
[22] Raheem, A. A. and Kareem, M. A. Optimal raw material mix for the production of rice husk ash blended cement. Int J Sustain Constr Eng Technol. 7,2 (2017a).
[23] Raheem, A. A. and Kareem, M. A. Chemical composition and physical characteristics of rice husk ash blended cement. Int J Eng Res Afr. 32 (2017b) 25–35.
[24] Raisi, E. M, Amiri, J. V, Davoodi, M. R. Mechanical performance of self-compacting concrete incorporating rice husk ash. Constr Build Mater. 177 (2018) 148–157. . https://doi.org/10.1016/j.conbuildmat
[25] Seyed, A. Z., Farshad, A., Farzan, D. and Mojtaba A. Rice husk ash as a partial replacement of cement in high strength concrete containing micro silica. Case Stud Constr Mater. 7 (2017) 73-81. https://doi.org/10.1016/j.cscm
[26] Shafigh, P., Mahmud, H. B. and Jumaat, M. Z. Effect of calcium nitrate on workability and early-age strength of high-performance concrete. Mater Des. 32,5 (2011) 3187-3193. https://doi.org/10.1016/j.matdes
[27] Swetha, R., Rani, M. S. and Raju, U. Experimental works on self-compacting concrete by partial replacement of rice husk ash with subjected to acid attack. Int J Innov Technol Explor Eng. 9 (2020) 664–667. https://doi.org/10.35940/ijitee
[28] Tayeh, B. A., Alyousef, R., Alabduljabbar, H. and Alaskar, A. Recycling of rice husk waste for a sustainable concrete: A critical review. J Clean Prod. 312 (2021) 127-134. https://doi.org/10.1016/j.jclepro
[29] Teo, D. C. L., Mannan, M. A., Kurian, V. J. and Ganapathy, C. Lightweight concrete made from oil palm shell (OPS): Structural bond and durability properties. Build Environ. 42 (2007) 2614–2621. https://doi.org/10.1016/j.buildenv
[30] Thomas, M. D. A., Shehata, M. H. and Shashiprakash, S. G. Use of supplementary cementing materials in concrete: Basics, benefits, and the influence of calcium nitrate on workability. ACI Mater J. 109,6 (2012) 767-776.
[31] Zhang, M. H., Islam, J. and Peethamparan, S. Use of calcium nitrate as an accelerator in combination with supplementary cementitious materials. Cem Concr Compos. 60 (2015) 50-59. https://doi.org/10.1016/j.cemconcomp