Massive nitrogen super-saturation into CoCrMo Alloys for improvement of tribological performance

Massive nitrogen super-saturation into CoCrMo Alloys for improvement of tribological performance

AIZAWA Tatsuhiko, FUNAZUKA Tatsuya, SHIRATORI Tomomi, SUZUKI Yohei

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Abstract. The cobalt-chromium-molybdenum (CoCrMo) superalloys have been utilized in the dental, knee, and hip arthroplasty applications because of their unique combination of high strength, high wear and corrosion resistance. A massive nitrogen supersaturation (MNS) process was proposed as a surface treatment to improve these strength, hardness and ductility, further needed for hip replacement and dental prosthesis. CoCrMo disc specimens were prepared for plasma immersion nitriding at 673 K for 21.6 ks by 50 Pa. The nitrogen solute uniformly distributed in the MNS-layer with the average content of 5 mass%. Higher surface hardness than 1550 HV was attained under application of 10 N. The maximum friction coefficient was halved before and after MNS and this low frictional state with μ< 0.45 was preserved although the sliding condition by 0.1 m/s. Keywords
Plasma Nitriding, Cocrmo Alloys, Massive Nitrogen Interstitials, Low Friction and Wear

Published online 4/24/2024, 11 pages
Copyright © 2024 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: AIZAWA Tatsuhiko, FUNAZUKA Tatsuya, SHIRATORI Tomomi, SUZUKI Yohei, Massive nitrogen super-saturation into CoCrMo Alloys for improvement of tribological performance, Materials Research Proceedings, Vol. 41, pp 1248-1258, 2024

DOI: https://doi.org/10.21741/9781644903131-139

The article was published as article 139 of the book Material Forming

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

References
[1] Bandyopaghyay, A., Traxel, K. D., Avila, J. D., Mitra, I., Bose. S., CoCr alloys. Biomaterials Science, 4th Ed. Academic Press 1.3.3C (2020) pp. 257-269. https://doi.org/10.1016/B978-0-12-816137-1.00020-9
[2] Carek, A.; Babic, J. Z., Schauperl, Z., Tomislav, B., Mechanical properties of Co-Cr alloys for metal base framework. Int. J. Prosthodont. Restor. Dent. 1 (2011) pp. 13-19. https://doi.org/10.5005/jp-journals-10019-1003
[3] Devine, T. M., Wulff, J., Cast vs. wrought cobalt-chromium surgical implant alloys. J. Biomed. Mater. Res. 9 (1975) pp. 151-167. https://doi.org/10.1002/jbm.820090205
[4] Lee, S., Nomura, N., Chiba, A., Significant improvement in mechanical properties of biomedical Co-Cr-Mo alloys with combination of N addition and Cr-enrichment. Materials Transactions. 2 (2008) pp.260-264. https://doi.org/10.2320/matertrans.MRA2007220
[5] Longquan, S.; Northwood, D., Cao, Z., The properties of a wrought biomedical Cobalt-Chromium alloy. J. Mat. Sci. 18 (1994) pp. 1233-1238. https://doi.org/10.1007/BF00975070
[6] Cheng, H.; Xu, M., Zhang, H., Wu, W., Zheng, M., Li, X., Cyclic fatigue properties of Cobalt-Chromium alloy clasps for partial removable dental protheses. J. Prosthetic Dent. 104 (2010) pp. 389-396. https://doi.org/10.1016/S0022-3913(10)60173-4
[7] Wang Q.; Zhang L., Shen H., Microstructure analysis of plasma nitrided cast/forged CoCrMo alloys. Surf. Coat. Technol. 205 (7) (2010) pp. 2654-2660. https://doi.org/10.1016/j.surfcoat.2010.10.031
[8] Dong H.; S-phase surface engineering of Fe-Cr, Co-Cr and Ni-Cr alloys. Int. Mater. Rev. 55 (2) (2011) pp. 65-98. https://doi.org/10.1179/095066009X12572530170589
[9] Shukla K.; Sugumaran A. A., Khan I., Ehiasarian A. P., Hovsepian P. E., Low pressure plasma nitrided CoCrMo alloy utilizing HIPIMS discharge for biomedical applications. J. Mech. Behavior of Biomedical Materials. 111 (2020) 104110. https://doi.org/10.1016/j.jmbbm.2020.104004
[10] Aizawa T.; Funazuka T., Shiratori T., Suzuki Y., Massive nitrogen supersaturation to CoCrMo alloys for surface microstructure control. Academia Mater. Sci. 1 (2023) pp. 1-9. https://doi.org/10.20935/AcadMatSci6139
[11] Farghali A., Aizawa T., Yoshino T., Microstructure/mechanical characterization of plasma nitrided fine-grain austenitic stainless steels in low temperature. Nitrogen 2 (2021) pp. 244-258. https://doi.org/10.3390/nitrogen2020016
[12] Aizawa T., Rsadi I., Yunata E. E., High density RF-DC plasma nitriding under optimized conditions by plasma diagnosis. Appl. Sci. 12, 3706 (2022) pp. 1-12. https://doi.org/10.3390/app12083706
[13] He K., Chen N., Wang C., Wei L., Chen J., Method for determining crystal grain size by X-ray diffraction. Crystal Res. Technol. 53 (1) (2018) 157. https://doi.org/10.1002/crat.201700157
[14] Frueh P., Heine A., Weber K. E., Wickert M., Effective depth-of-penetration range due to hardness variation for different lots of nominally identical target material. Defence Technol. 12 (2) (2016) pp. 171-176. https://doi.org/10.1016/j.dt.2015.10.002
[15] Fu J., Lyu D., Zhao J., Tribological characteristics of hard-to-hard matching materials of cylinder block/valve plate interface in electro-hydrostatic actuator pumps. J. Mech. Eng. Sci. 27 (2023) 61-68.
[16] Aizawa T., Shiratori T., Komatsu T., Integrated manufacturing of fine-grained stainless steels for industries and medicals. Chapter 1 in Engineering Steels and High Entropy-Alloys. IntechOpen, London, UK (2020) pp. 3-26. https://doi.org/10.5772/intechopen.89754
[17] Aizawa T., Micro-/meso-structure control of multi-hostmetal alloys by massive nitrogen supersaturation. J. Materials (2024) (in press). https://doi.org/10.3390/ma17061294
[18] Funazuka T., Horiuchi S., Dohda K., Shiratori T., Effect of CoCrMo die with nanotexture applied on micro-extrudability of micro backward extrusion of AA6063. Proc. WCMNM2023 (19th September, 2023; Evanston, Chicago, USA) 2023; 1-4.
[19] Silicolloy, https://www.silicolloy.co.jp/tribology/friction_wear_ballon-suj2/. (Retrieved at 2023/12/15).