Kinetic study of combined steam and CO2 reforming of methane over Ni-Sr/MgO-ZrO2 catalyst

Kinetic study of combined steam and CO2 reforming of methane over Ni-Sr/MgO-ZrO2 catalyst

AHMAD Salam Farooqi, BAWADI Abdullah, FREDERIC Marias, AMANDA Yap Yi Tong, UMAIR Ishtiaq

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Abstract. Combined steam and CO2 reforming of methane (CSCRM) has gained increasing attention as a potential solution to mitigate global warming and addressing the demand for alternative energy resources. In this study, the reaction kinetics of CSCRM over high-performance Ni-Sr/MgO-ZrO2 bimetallic catalyst is investigated in a fixed bed reactor. The rate of reaction was analyzed at a temperatures ranging from 700-800℃ and reactant partial pressures of CH4, CO2 and H2O ranging from 5-50 kPa. The apparent activation energies for CH4 and CO2 consumption were found to be 20.94 kJ/mol and 27.53 kJ/mol respectively. The experimental results obtained were then fitted with a Power Law kinetic model and showed good agreement with R2 values of 0.86-0.91.

Keywords
Reaction Kinetics, CSCRM, Bimetallic Catalyst, Activation Energy, Power Law

Published online 5/20/2023, 9 pages
Copyright © 2023 by the author(s)
Published under license by Materials Research Forum LLC., Millersville PA, USA

Citation: AHMAD Salam Farooqi, BAWADI Abdullah, FREDERIC Marias, AMANDA Yap Yi Tong, UMAIR Ishtiaq, Kinetic study of combined steam and CO2 reforming of methane over Ni-Sr/MgO-ZrO2 catalyst, Materials Research Proceedings, Vol. 29, pp 407-415, 2023

DOI: https://doi.org/10.21741/9781644902516-46

The article was published as article 46 of the book Sustainable Processes and Clean Energy Transition

Content from this work may be used under the terms of the Creative Commons Attribution 3.0 license. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.

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