Green Organic Inhibitors for Corrosion Protection
Y.V.D. Nageswar, V.J. Rao
Plants are a rich source of different varied organic compounds. Due to the important applications of naturally occurring chemicals their derivatives are also pursued for modifying and potentiating the activities of natural products. Metallic corrosion is a natural process resulting in heavy losses in various fields. Non hazardous and non toxic corrosion inhibitors gained significance due to the environmental regularities and guidelines issued in the course of saving the pristine nature of environment and to maintain the sustainability of our earth. Green corrosion inhibitors play a potential role for the above said cause. Recent research contributions on green corrosion inhibitors from the active researchers in the concerned expertise are presented briefly here to give an idea about the current research activity across the world.
Keywords
Phytochemicals, Surfactants, Protective Film, Inhibition Efficacy, Corrosion Inhibition, Physisorption, Chemisorption, Corrosion Rate, Inhibitor Concentration, Electrochemical Impedance Spectroscopy
Published online 6/5/2021, 29 pages
Citation: Y.V.D. Nageswar, V.J. Rao, Green Organic Inhibitors for Corrosion Protection, Materials Research Foundations, Vol. 107, pp 101-129, 2021
DOI: https://doi.org/10.21741/9781644901496-5
Part of the book on Sustainable Corrosion Inhibitors
References
[1] Rodríguez-Torres, O. Olivares-Xometl, M.G. Valladares-Cisneros, J.G. González-Rodríguez, Effect of Green Corrosion Inhibition by Prunuspersica on AISI 1018 Carbon Steel in 0.5M H2SO4, Int. J. Electrochem. Sci. 13 (2018) 3023-3049. https://doi.org/10.20964/2018.03.40
[2] G. Subramanian, R.S. Kannan, M. Malarvizhi, P. Muthirulan, A novel eco-friendly corrosion inhibitor for mild steel protection in two different aggressive artificial corrosive medium, J. Chem. Pharm. Res. 10 (2018) 155-163.
[3] L.A.L. Guedes, K.G. Bacca, N.F. Lopes, E.M. da Costa, Tannin of Acacia mearnsiias green corrosion inhibitor for AA7075-T6 aluminium alloy in acidic medium, Mater. Corros. 70 (2019) 1288-1297. https://doi.org/10.1002/maco.201810667
[4] H. Taoui, H. Bentrah, A. Chala, M. Djellab, Bark resin of Schinusmolle as an eco-friendly inhibitor for API 5L X70 pipeline steel in HCl medium, Mater. Corros. 70 (2019) 511-520. https://doi.org/10.1002/maco.201810477
[5] A.S. Yaro, A.A. Khadom, R.K. Wael, Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid, Alexandrai Eng. J. 52 (2013) 129-135. https://doi.org/10.1016/j.aej.2012.11.001
[6] Aiad, S.M. Shaban, A.H. Elged, O.H. Aljoboury, Cationic surfactant based on alignate as green corrosion inhibitors for the mild steel in 1.0 M HCl, Egypt. J. Petrol. 27 (2018) 877-885. https://doi.org/10.1016/j.ejpe.2018.01.003
[7] M.T. Saeed, M. Saleem, S. Usmani, I.A. Malik, F.A. Al-Shammari, K.M. Deen, Corrosion inhibition of mild steel in 1 M HCl by sweet melon peel extract, J. King Saud Univ. Sci. 31 (2019) 1344-1351. https://doi.org/10.1016/j.jksus.2019.01.013
[8] A.A. Khadom, A.N. Abd, N.A. Ahmed, Xanthium Strumarium leaves extracts as a friendly corrosion inhibitor of low carbon steel in hydrochloric acid: kinetics and mathematical studies; South Afr. J. Chem. Eng. 25 (2018) 13-21. https://doi.org/10.1016/j.sajce.2017.11.002
[9] N. Raghavendra, J.I Bhat, Red arecanut seed extract as a sustainable corrosion inhibitor for aluminum submerged in acidic corrodent: An experimental approach towards zero environmental impact, Periodica. Polytechnica. Chem. Eng. 62 (2018) 351-358. https://doi.org/10.3311/PPch.10686
[10] I. Pradipta, D. Kong, J. Ban, L. Tan, Natural organic antioxidants from green tea form a protective layer to inhibit corrosion of steel reinforcing bars embedded in mortar, Construct. Build. Mater. 221 (2019) 351-362. https://doi.org/10.1016/j.conbuildmat.2019.06.006
[11] R. Idouhli, Y. Koumya, M. Khadiri, A. Aityoub, A. Abouelfda, A. Benyaich, Inhibitory effect of Senecioanteuphorbium as green corrosion inhibitor for S300 steel, Int. J. Ind. Chem. 10 (2019) 133-143. https://doi.org/10.1007/s40090-019-0179-2
[12] A. Rodríguez-Torres, M.G. Valladares-Cisneros, C. Cuevas-Arteaga, M.A. Veloz-Rodríguez, Study of green corrosion inhibition on AISI 1018 carbon steel in sulfuric acid using crataegusmexicana as eco-friendly inhibitor. J. Mater. Environ. Sci. 10 (2019) 101-112.
[13] S. Umoren, Z.M. Gasem, Ime B Obot, Natural products for materials protection: Inhibition of mild steel corrosion by date palm seed extracts in acid media, Ind. Eng. Chem. Res. 52 (2013) 14855-148655. https://doi.org/10.1021/ie401737u
[14] P.B. Raja, M. Fadaeinasab, A.K. Qureshi, A.A. Rahim, H. Osman, M. Litaudon, K. Awang, Evaluation of green corrosion inhibition by alkaloid extracts of Ochrosiaoppositifolia and isoreserpiline against mild steel in 1M HCl medium, Ind. Eng. Chem. 52 (2013) 10582-10593. https://doi.org/10.1021/ie401387s
[15] N.I.N. Haris, S. Sobri, N. Kassim, Oil palm empty fruit bunch extract as green corrosion inhibitor for mild steel in hydrochloric acid solution: Central composite design optimization, Mater. Corros. 70 (2019) 1111-1119. https://doi.org/10.1002/maco.201810653
[16] R. Haldhar, D. Prasad, A. Saxena1, P. Singh, valerianawillichiroots extract as a green & sustainable corrosion inhibitor for mild steel in acidic environment: experimental and theoretical study, Mater. Chem. Frontiers 2 (2018) 1225-1237. https://doi.org/10.1039/C8QM00120K
[17] K. Zhang, W. Yang, B. Xu, X. Yin, Y. Chen, Y. Liu, Green synthesis of novel schiff bases as eco-friendly corrosion inhibitors for mild steel in hydrochloric acid, Chem. Select 3 (2018) 12486-12494. https://doi.org/10.1002/slct.201802915
[18] O. Kaczerewska1, R. Leiva-Garcia, R. Akid, B. Brycki, I. Kowalczyk, T. Pospieszny, Heteroatoms and π electrons as favorable factors for efficient corrosion protection, Mater. Corros. 70 (2019) 1099-1110. https://doi.org/10.1002/maco.201810570
[19] S. Varvara, R. Bostan, L. Gaina, L.M. Muresan, Thiadiazole derivatives as inhibitors for acidic media corrosion of artificially patinated bronze, Mater. Corros. 65 (2014) 1202-1214. https://doi.org/10.1002/maco.201307072
[20] T.M.A. Eldebss, A.M. Farag, A.Y.M. Shamy, Synthesis of some benzimidazole-based heterocycles and their application as copper corrosion inhibitors, J. Heterocyclic Chem. 56 (2019) 371-390. https://doi.org/10.1002/jhet.3407
[21] W. Zhang, H.J. Li, A. Wang, C. Ma, Z. Wang, H. Zhang, Y.C. Wu, Synergistic inhibition effect of N‐(furan‐2‐ylmethyl)‐7 H‐purin‐6‐amine and iodide ion for mild steel corrosion in 1 mol/L HCl, Mater. Corros. 70 (2019) 1-10. https://doi.org/10.1002/maco.201911146
[22] E.A. Yaqo, R.A. Anaee, M.H. Abdulmajeed, I.H.R. Tomi, M.M. Kadhim, Aminotriazole derivative as anti-corrosion material for iraqi kerosene tanks: Electrochemical, computational and the surface study, Chem. Select 4 (2019) 9883-9892. https://doi.org/10.1002/slct.201902398
[23] H. Liu, J. Hu, X. Zhou, D. Liu, B. Xu, Y. Zhou, Synthesis, corrosion inhibition performance and biodegradability of novel alkyl hydroxyethylimidazoline salts, J. Surface Deteg. 18 (2015) 1025-1031. https://doi.org/10.1007/s11743-015-1725-3
[24] T.K.A. Hoang, T.N.L. Doan, J.H. Cho, J.Y.J. Su, C. Lee, C. Lu, P. Chen, Sustainable gel electrolyte containing pyrazole as corrosion inhibitor and dendrite suppressor for aqueous Zn/LiMn2O4 battery, Chem. Sus. Chem. 10 (2017) 2816-2822. https://doi.org/10.1002/cssc.201700441
[25] I. Aiad, S.M. Shaban, A.H. Elged, O.H. Aljoboury, Cationic surfactant based on alignate as green corrosion inhibitors for the mild steel in 1.0 M HCl, Egypt. J. Petrol. 27 (2018) 877-885. https://doi.org/10.1016/j.ejpe.2018.01.003
[26] P. Dohare, M.A. Quraishi, C. Vermac, H. Lgaze, R. Salghif, E.E. Ebenso, Ultrasound induced green synthesis of pyrazolo-pyridines as novel corrosion inhibitors useful for industrial pickling process: Experimental and theoretical approach, Results Phys. 13 (2019) 102344. https://doi.org/10.1016/j.rinp.2019.102344
[27] Verma, E.E. Ebenso, L.O. Olasunkanmi, M.A. Quraishi, I.B. Obot, Adsorption behavior of glucosamine based pyrimidinefusedheterocycles as green corrosion inhibitors for mild steel: Experimental and theoretical studies, J. Phys. Chem. C, 120 (2016) 11593-11611. https://doi.org/10.1021/acs.jpcc.6b04429
[28] Lin, Y. Zuo, Corrosion inhibition of carboxylate inhibitors with different alkylene chain lengths on carbon steel in an alkaline solution, RSC Adv. 9 (2019) 7065-7077. https://doi.org/10.1039/C8RA10083G
[29] F. Yang, T. Liu, J. Li, S. Qiu, H. Zhao, Anticorrosive behavior of a zinc-rich epoxy coating containing sulfonatedpolyaniline in 3.5% NaCl solution, RSC Adv. 8 (2018) 13237-13247. https://doi.org/10.1039/C8RA00845K
[30] N. Wei, Y. Jiang, Z. Liu, Y. Ying, X. Guo, Y. Wu, Y. Wen, H. Yang, 4-Phenylpyrimidine monolayer protection of a copper surface from salt corrosion; RSC Adv. 8 (2018) 7340-7349. https://doi.org/10.1039/C7RA12256J
[31] E.D. Akpan, I.O. Isaac, L.O. Olasunkanmi, E.E. Ebenso, E.S.M. Sherif, Acridine-based thiosemicarbazones as novel inhibitors of mild steel corrosion in 1 M HCl: Synthesis, electrochemical, DFT and Monte Carlo simulation studies, RSC Adv., 9 (2019) 29590-29599. https://doi.org/10.1039/C9RA04778F
[32] J. Haque, V. Srivastava, D.S. Chauhan, H. Lgaz, M.A. Quraishi, Microwave-induced synthesis of chitosan schiff bases and their application as novel and green corrosion inhibitors: Experimental and theoretical approach, ACS Omega 3 (2018) 5654-5668. https://doi.org/10.1021/acsomega.8b00455
[33] X. Gao, S. Liu, H.F. Lu, F. Gao, H. Ma, Corrosion inhibition of iron in acidic solutions by monoalkyl phosphate esters with different chain lengths, Ind. Eng. Chem. 54 (2015) 1941-1952. https://doi.org/10.1021/ie503508h
[34] A.R. Estrada, V.Y.M. Cervantes, I. Elizalde, A.M. Robledo, L.S.Z. Rivera, D.A.N. Álvarez, F. Farelas, R.H. Altamirano, Development of a zwitterionic compound derived from β‑amino acid as a green inhibitor for co2 corrosive environments; ACS Sustain. Chem. Eng. 5 (2017) 10396-10406. https://doi.org/10.1021/acssuschemeng.7b02434
[35] N. Weder, R.A. Alberto, R. Koitz, Thiourea derivatives as potent inhibitors of aluminium corrosion: Atomic-level insight into adsorption and inhibition mechanisms, J. Phys. Chem. C 120 (2016) 1770-1777. https://doi.org/10.1021/acs.jpcc.5b11750
[36] P.B. Raja, M. Fadaeinasab, A.K. Qureshi, A.A. Rahim, H. Osman, M. Litaudon, K. Awang, Evaluation of green corrosion inhibition by alkaloid extracts of Ochrosiaoppositifolia and isoreserpiline against mild steel in 1M HCl medium, Ind. Eng. Chem., 52 (2013) 10582-10593. https://doi.org/10.1021/ie401387s
[37] Cano, P. Pinilla, J.L. Polo, J.M. Bastidas, Copper corrosion inhibition by fast green, fuchsin acid and basic compounds in citric acid solution, Mater. Corros. 54 (2003) 222-228. https://doi.org/10.1002/maco.200390050
[38] S.E. Kaskah, M. Pfeiffer, H. Klock, H. Bergen, G. Ehrenhaft, P.F.J. Gollnick, C.B. Fischer, Surface protection of low carbon steel with N-acyl sarcosine derivatives as green corrosion inhibitors; Surfaces and Interfaces, 9 (2017) 70-78. https://doi.org/10.1016/j.surfin.2017.08.002
[39] R.S. Erami, M. Amirnasr, S. Meghdadi, M. Talebian, H. Farrokhpour, K. Raeissi, Carboxamide derivatives as new corrosion inhibitors for mild steel protection in hydrochloric acid solution, Corros. Sci. 151 (2019) 190-197. https://doi.org/10.1016/j.corsci.2019.02.019
[40] I.B. Onyeachu, I.B. Obot, A.A. Sorour, M.I.A. Rashid, Green corrosion inhibitor for oilfield application I: Electrochemical assessment of 2-(2-pyridyl) benzimidazole for API X60 Steel under sweet environment in NACE brine ID196, Corros. Sci. 150 (2019) 183-193. https://doi.org/10.1016/j.corsci.2019.02.010
[41] Sukul, A. Pal, S.K. Saha, S. Satpati, U. Adhikari, P. Banerjee, Newly synthesized quercetin derivatives as corrosion inhibitor for mild steel in 1 M HCl: Combined experimental and theoretical investigation, Phys. Chem. Chem. Phys. 20 (2018) 6562-6574. https://doi.org/10.1039/C7CP06848D
[42] M. Yadav, R.R. Sinha, S. Kumar, T.K. Sarkar, Corrosion inhibition effect of spiropyrimidinethiones on mild steel in 15% HCl solution insight from: Electrochemical and quantum studies, RSC Adv. 5 (2015) 70832-70848. https://doi.org/10.1039/C5RA14406J
[43] Chiter, M.L. Bonnet, C.L. Dufaure, H. Tangb, N. Pe’be’re, Corrosion protection of Al(111) by 8-hydroxyquinoline: a comprehensive DFT study, Phys. Chem. Chem. Phys. 20 (2018) 21474-21486. https://doi.org/10.1039/C8CP03312A
[44] A.K. Singh, S. Thakur, B. Pani, G. Singh, Green synthesis and corrosion inhibition study of 2-amino-N’-(thiophen-2-yl) methylene) benzohydrazide, New J. Chem. 42 (2018) 2113-2124. https://doi.org/10.1039/C7NJ04162D
[45] N.K. Gupta, M.A. Quraishi, C. Verma, A.K. Mukherjee, Green Schiff’s bases as corrosion inhibitors for mild steel in 1 M HCl solution: Experimental and Theoretical approach, RSC Adv. 6 (2016) 102076-102087. https://doi.org/10.1039/C6RA22116E
[46] C. Verma, L.O. Olasunkanmi, I. B. Obot, E.E. Ebenso, M.A. Quraishi, 2, 4-diamino-5-(phenylthio)-5H-chromeno [2, 3-b] pyridine-3-carbonitriles as green and effective corrosion inhibitors: Gravimetric, electrochemical, surface morphology and theoretical studies, RSC Adv. 6 (2016) 53933-53948. https://doi.org/10.1039/C6RA04900A
[47] M. Prabakaran, S.H. Kim, A. Sasireka, V. Hemapriya, I.M. Chung, β-Sitosterol isolated from rice hulls as an efficient corrosion inhibitor for mild steel in acidic environments, New J. Chem. 41 (2017) 3900-3907. https://doi.org/10.1039/C6NJ03760G
[48] M.L. Zheludkevich, J. Tedim, C.S.R. Freire, S.C.M. Fernandes, S. Kallip, A. Lisenkov, A. Gandini, M.G.S. Ferreira, Self-healing protective coatings with ”green” chitosan based pre-layer reservoir of corrosion inhibitor, J. Mater. Chem. 21 (2011) 4805-4812. https://doi.org/10.1039/c1jm10304k
[49] J. Haque, V. Srivastava, C. Verma, H. Lgaz, R. Salghi, M.A. Quraishi, N-Methyl-N, N, N-trioctylammonium chloride as novel and green corrosion inhibitor for mild steel in acid chloride medium: Electrochemical, DFT and MD studies, New J. Chem. 41 (2017) 13647-13662. https://doi.org/10.1039/C7NJ02254A
[50] M. Yadav, T.K. Sarkar1, I.B. Obot, Carbohydrate compounds as green corrosion inhibitor: Electrochemical, XPS, DFT and molecular dynamics simulation studies, RSC Adv. 6 (2016), 110053-110069. https://doi.org/10.1039/C6RA24026G