Polyoxometalate-Based Metal-Organic Framework Composites

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Polyoxometalate-Based Metal-Organic Framework Composites

Yunpeng He, Shuijin Yang

A series of polyoxometalates(POMs)-based Metal-Organic Frameworks (MOFs) were synthesized through direct incorporation between POMs and MOFs. In these compounds, the catalytically active polyanions as noncoordinating guests in the metal-organic frameworks host matrix. To overcome the difficulties of lack of sufficient thermal and chemical stability,a lot of research was done to introduce POMs to different MOFs for constructing various POM supporting MOFs with desired properties. POM based MOFs as a new type of functional materials developed rapidly, and is used in electrocatalysts, photocatalysis, oxidative desulfurization, lithium storage and adsorption.

Keywords
Polyoxometalates (POMs), Metal-Organic Frameworks, Catalysts, Oxidative Desulfurization, Adsorption

Published online 6/30/2019, 19 pages

Citation: Yunpeng He, Shuijin Yang, Polyoxometalate-Based Metal-Organic Framework Composites, Materials Research Foundations, Vol. 53, pp 257-275, 2019

DOI: https://doi.org/10.21741/9781644900291-12

Part of the book on Metal-Organic Framework Composites

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